Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3190
Title: Polymerization mechanism of 1-[(butylsulfi(o)nyl)metyl]-4-(halomethyl)benezene: The effect of polarizer and leaving group
Authors: Issaris, A
VANDERZANDE, Dirk 
ADRIAENSENS, Peter 
GELAN, Jan 
Issue Date: 1998
Publisher: AMER CHEMICAL SOC
Source: MACROMOLECULES, 31(14). p. 4426-4431
Abstract: A synthesis route to soluble high molecular weight poly(p-xylylene) derivatives has been investigated. This method provides a versatile route to poly(phenylenevinylene) (PPV) from a precursor polymer that is amenable to the conventional nonaqueous processing techniques. To investigate the mechanism in the solvent mixture, monomethylformamide (MMF)/CH2Cl2 (60/40), the influence of the leaving group and polarizer of the monomer was studied. The evaluation of the molecular weight of the polymer, the polymer yield, and the residual low molecular weight fraction indicates that only the kind of polarizer has an effect on the reaction in contrast with the leaving group, having no observable effect.
Notes: Limburgs Univ Ctr, Inst Mat Res, Lab Organ & Polymer Chem, Div Chem, B-3590 Diepenbeek, Belgium.Vanderzande, D, Limburgs Univ Ctr, Inst Mat Res, Lab Organ & Polymer Chem, Div Chem, Univ Campus, B-3590 Diepenbeek, Belgium.
Document URI: http://hdl.handle.net/1942/3190
ISI #: 000074853700004
Type: Journal Contribution
Validations: ecoom 1999
Appears in Collections:Research publications

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