Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/32949
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dc.contributor.authorGrote, Roos-
dc.contributor.authorHabets, Roberto-
dc.contributor.authorRohlfs, Jelle-
dc.contributor.authorSastre, Francesc-
dc.contributor.authorMeulendijks, Nicole-
dc.contributor.authorXu, Man-
dc.contributor.authorVerheijen, Marcel A.-
dc.contributor.authorELEN, Ken-
dc.contributor.authorHARDY, An-
dc.contributor.authorVAN BAEL, Marlies-
dc.contributor.authorden Hartog, Tim-
dc.contributor.authorBUSKENS, Pascal-
dc.date.accessioned2020-12-15T15:00:36Z-
dc.date.available2020-12-15T15:00:36Z-
dc.date.issued2020-
dc.date.submitted2020-11-17T13:15:51Z-
dc.identifier.citationChemCatChem, 12 (22) , p. 5618 -5622-
dc.identifier.urihttp://hdl.handle.net/1942/32949-
dc.description.abstractPlasmon catalysis is an interesting technology concept for powering chemical processes with light. Here, we report the use of various Al2O3-supported Ru spheroidal nanoparticles as catalyst for the low-temperature conversion of CO(2)and H(2)to CH4(Sabatier reaction), using sunlight as energy source. At high loadings of Ru spheroidal nanoparticles (5.9 % w/w), we observe a sharp increase in the rate of the sunlight powered reaction when compared to the reaction in dark at the same catalyst bed temperature. Based on our results we exclude plasmon coupling as cause, and attribute the rate enhancement to collective photothermal heating of the Al2O3-supported Ru nanoparticles.-
dc.description.sponsorshipR.H., J.R., F.S., N.M., M.X., P.B. (all TNO), K.E. (IMEC), A.H., M.K.V.B. (both Hasselt University) and T.d.H. (Zuyd University of Applied Sciences) acknowledge financial support from the European Fund for Regional Development through the cross-border collaborative Interreg V program Flanders-The Netherlands (project LUMEN), co-financed by the Belgian province of Limburg and the Dutch provinces of Limburg and Noord-Brabant. M.A.V. acknowledges Solliance and the Dutch province of Noord-Brabant for funding the TEM facility.-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.rights2020 The Authors. Published by Wiley-VCH GmbH. This is an open accessarticle under the terms of the Creative Commons Attribution License, whichpermits use, distribution and reproduction in any medium, provided theoriginal work is properly cited-
dc.subject.otherplasmon catalysis-
dc.subject.otherSabatier reaction-
dc.subject.othercarbon dioxide-
dc.subject.othersunlight-
dc.subject.othercollective photothermal effect-
dc.titleCollective photothermal effect of Al2O3-supported spheroidal plasmonic Ru nanoparticle catalysts in the sunlight-powered Sabatier reaction-
dc.typeJournal Contribution-
dc.identifier.epage5622-
dc.identifier.issue22-
dc.identifier.spage5618-
dc.identifier.volume12-
local.format.pages6-
local.bibliographicCitation.jcatA1-
dc.description.notesden Hartog, T; Buskens, P (corresponding author), Netherlands Org Appl Sci Res TNO, High Tech Campus 25, NL-5656 AE Eindhoven, Netherlands.; den Hartog, T; Buskens, P (corresponding author), Zuyd Univ Appl Sci, Appl Sci Acad, Nieuw Eyckholt 300, NL-6400 AN Heerlen, Netherlands.; Buskens, P (corresponding author), Hasselt Univ, Inst Mat Res Design & Synth Inorgan Mat DESINe, Agoralaan Bldg D, B-3590 Diepenbeek, Belgium.-
dc.description.notestim.denhartog@tno.nl; pascal.buskens@tno.nl-
dc.description.otherden Hartog, T; Buskens, P (corresponding author), Netherlands Org Appl Sci Res TNO, High Tech Campus 25, NL-5656 AE Eindhoven, Netherlands ; Zuyd Univ Appl Sci, Appl Sci Acad, Nieuw Eyckholt 300, NL-6400 AN Heerlen, Netherlands ; Hasselt Univ, Inst Mat Res Design & Synth Inorgan Mat DESINe, Agoralaan Bldg D, B-3590 Diepenbeek, Belgium. tim.denhartog@tno.nl; pascal.buskens@tno.nl-
local.publisher.placePOSTFACH 101161, 69451 WEINHEIM, GERMANY-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1002/cctc.202000795-
dc.identifier.isiWOS:000565683300001-
dc.contributor.orcidVerheijen, Marcel/0000-0002-8749-7755; Meulendijks,-
dc.contributor.orcidNicole/0000-0002-8911-5685; Xu, Man/0000-0001-6920-1386-
local.provider.typewosris-
local.uhasselt.uhpubyes-
local.description.affiliation[Grote, Roos; Habets, Roberto; Rohlfs, Jelle; Sastre, Francesc; Meulendijks, Nicole; Xu, Man; den Hartog, Tim; Buskens, Pascal] Netherlands Org Appl Sci Res TNO, High Tech Campus 25, NL-5656 AE Eindhoven, Netherlands.-
local.description.affiliation[Grote, Roos; den Hartog, Tim; Buskens, Pascal] Zuyd Univ Appl Sci, Appl Sci Acad, Nieuw Eyckholt 300, NL-6400 AN Heerlen, Netherlands.-
local.description.affiliation[Verheijen, Marcel A.] Eurofins Mat Sci, High Tech Campus 11, NL-5656 AE Eindhoven, Netherlands.-
local.description.affiliation[Verheijen, Marcel A.] Eindhoven Univ Technol, Dept Appl Phys, NL-5600 MB Eindhoven, Netherlands.-
local.description.affiliation[Elen, Ken; Hardy, An; Van Bael, Marlies K.; Buskens, Pascal] Hasselt Univ, Inst Mat Res Design & Synth Inorgan Mat DESINe, Agoralaan Bldg D, B-3590 Diepenbeek, Belgium.-
local.description.affiliation[Elen, Ken; Hardy, An; Van Bael, Marlies K.] IMEC VZW, IMOMEC Associated Lab, Wetenschapspk 1, B-3590 Diepenbeek, Belgium.-
item.contributorGrote, Roos-
item.contributorHabets, Roberto-
item.contributorRohlfs, Jelle-
item.contributorSastre, Francesc-
item.contributorMeulendijks, Nicole-
item.contributorXu, Man-
item.contributorVerheijen, Marcel A.-
item.contributorELEN, Ken-
item.contributorHARDY, An-
item.contributorVAN BAEL, Marlies-
item.contributorden Hartog, Tim-
item.contributorBUSKENS, Pascal-
item.validationecoom 2021-
item.fullcitationGrote, Roos; Habets, Roberto; Rohlfs, Jelle; Sastre, Francesc; Meulendijks, Nicole; Xu, Man; Verheijen, Marcel A.; ELEN, Ken; HARDY, An; VAN BAEL, Marlies; den Hartog, Tim & BUSKENS, Pascal (2020) Collective photothermal effect of Al2O3-supported spheroidal plasmonic Ru nanoparticle catalysts in the sunlight-powered Sabatier reaction. In: ChemCatChem, 12 (22) , p. 5618 -5622.-
item.accessRightsOpen Access-
item.fulltextWith Fulltext-
crisitem.journal.issn1867-3880-
crisitem.journal.eissn1867-3899-
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