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http://hdl.handle.net/1942/3296| Title: | Preparation of poly(isothianaphthene) from 2,5-bis(trialkylsilyl)isothianaphthenes | Authors: | Lapkowski, M KIEBOOMS, Rafael Pron, A Chauvet, O GELAN, Jan VANDERZANDE, Dirk Lefrant, S |
Issue Date: | 1997 | Publisher: | ELSEVIER SCIENCE SA LAUSANNE | Source: | SYNTHETIC METALS, 84(1-3). p. 413-414 | Abstract: | It is demonstrated that thee anodic oxidation of 2,5-bis(tert-butyldimethylsilyl) isothianaphthene in Bu4NBF4/nitrobenzene electrolyte results in the formation of poly( isothianaphthene) film with an average polymerization degree of 20. Disilylated isothianaphthene dimer and trimer do not polymerize in this electrolyte giving upon anodic oxidation stable radical cations and dications. | Notes: | TECH UNIV LODZ,DEPT TEXT ENGN & ENVIRONM SCI,PL-43300 BIELSKO BIALA,POLAND. UNIV LIMBURG,INST MAT ONDERZOEK,DEPT BSG,B-3590 DIEPENBEEK,BELGIUM. ACAD MIN & MET,DEPT MAT SCI & CERAM,PL-30059 KRAKOW,POLAND. TECH UNIV WARSAW,DEPT CHEM,PL-00664 WARSAW,POLAND. UNIV NANTES,UMR 110,LAB PHYS CRISTALLINE,IMN,F-44072 NANTES 03,FRANCE.Lapkowski, M, SILESIAN TECH UNIV,DEPT CHEM,PL-44100 GLIWICE,POLAND. | Keywords: | poly(isothianaphthene); electrochemistry; spectroelectrochemistry; Raman spectroelectrochemistry | Document URI: | http://hdl.handle.net/1942/3296 | DOI: | 10.1016/S0379-6779(97)80808-9 | ISI #: | A1997WW43100175 | Type: | Journal Contribution |
| Appears in Collections: | Research publications |
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