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http://hdl.handle.net/1942/3297| Title: | Polymerization of a p-quinodimethane derivative to a precursor of poly(p-phenylene vinylene) - Indications for a free radical mechanism | Authors: | Issaris, A VANDERZANDE, Dirk GELAN, Jan |
Issue Date: | 1997 | Publisher: | ELSEVIER SCI LTD | Source: | POLYMER, 38(10). p. 2571-2574 | Abstract: | A new synthetic route to high molecular weight poly(p-phenylene vinylene) derivatives-via a p-quinodimethane intermediate-has been investigated. Whether the polymerization is ionic or free radical has been under discussion for a long time. Strong indications for a self-initiating free radical mechanism for the polymerization are presented. (C) 1997 Elsevier Science Ltd. | Notes: | LIMBURGS UNIV CTR,INST MAT RES,DIV CHEM,LAB ORGAN & POLYMER CHE,,B-3590 DIEPENBEEK,BELGIUM. | Keywords: | poly(p-phenytene vinylene); radical mechanism; initiating particle | Document URI: | http://hdl.handle.net/1942/3297 | DOI: | 10.1016/S0032-3861(96)00468-5 | ISI #: | A1997WX11400035 | Type: | Journal Contribution |
| Appears in Collections: | Research publications |
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