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http://hdl.handle.net/1942/3339
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DC Field | Value | Language |
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dc.contributor.author | VAN DEN RUL, Heidi | - |
dc.contributor.author | YPERMAN, Jan | - |
dc.contributor.author | Buchanan, AC | - |
dc.contributor.author | Britt, PF | - |
dc.contributor.author | MAES, Inge | - |
dc.contributor.author | FRANCO, Dirk | - |
dc.contributor.author | MULLENS, Jules | - |
dc.contributor.author | VAN POUCKE, Lucien | - |
dc.date.accessioned | 2007-11-27T15:03:51Z | - |
dc.date.available | 2007-11-27T15:03:51Z | - |
dc.date.issued | 1997 | - |
dc.identifier.citation | ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 213. p. 32-FUEL | - |
dc.identifier.issn | 0065-7727 | - |
dc.identifier.uri | http://hdl.handle.net/1942/3339 | - |
dc.description.abstract | a kinetic study of AP-TPR-profile of silica immobilized thioanisole was carried out, resulting in a better understanding of the mechanistic behaviour of this model compound under the specified conditions. AP-TPR (Athmospheric Pressure - Temperature-Programmed Reduction) with potentiometric sulfur detection is a thermoanalytical method used to differentiate between sulfur forms in solids like coals. In this respect, sillica-immobilized thioanisole was recorded as a nonmelting calibrant. Several kinetic methods exist to analyze a heterogenous process involving a solid that is heated by a linear temperature programme. The isoconversial method can be considered as one of the most accurate. It was applied to to the AP-TPR-profile of thioanisole, showing the reduction of this compound very quickly becomes a diffusion-controlled reaction. Kinetic parameters are reported for this process under the AP-TPR-conditions. | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Mechanism of silica-immobilized thioanisole conversion during an AP-TPR experiment | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | FUEL | - |
dc.identifier.spage | 32 | - |
dc.identifier.volume | 213 | - |
local.format.pages | 1 | - |
dc.description.notes | LIMBURGS UNIV CENTRUM,LAB INORGAN & PHYS CHEM,B-3590 DIEPENBEEK,BELGIUM. OAK RIDGE NATL LAB,DIV CHEM & ANALYT SCI,OAK RIDGE,TN 37831. | - |
local.type.refereed | Refereed | - |
local.type.specified | Meeting Abstract | - |
dc.bibliographicCitation.oldjcat | A5 | - |
dc.identifier.isi | A1997WP18503319 | - |
item.accessRights | Closed Access | - |
item.fulltext | No Fulltext | - |
item.contributor | VAN DEN RUL, Heidi | - |
item.contributor | YPERMAN, Jan | - |
item.contributor | Buchanan, AC | - |
item.contributor | Britt, PF | - |
item.contributor | MAES, Inge | - |
item.contributor | FRANCO, Dirk | - |
item.contributor | MULLENS, Jules | - |
item.contributor | VAN POUCKE, Lucien | - |
item.fullcitation | VAN DEN RUL, Heidi; YPERMAN, Jan; Buchanan, AC; Britt, PF; MAES, Inge; FRANCO, Dirk; MULLENS, Jules & VAN POUCKE, Lucien (1997) Mechanism of silica-immobilized thioanisole conversion during an AP-TPR experiment. In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 213. p. 32-FUEL. | - |
Appears in Collections: | Research publications |
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