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http://hdl.handle.net/1942/35398
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DC Field | Value | Language |
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dc.contributor.author | VAN LANDEGHEM, Melissa | - |
dc.contributor.author | VAN GOMPEL, Wouter | - |
dc.contributor.author | HERCKENS, Roald | - |
dc.contributor.author | LUTSEN, Laurence | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.contributor.author | VAN DOORSLAER, Sabine | - |
dc.contributor.author | Goovaerts, Etienne | - |
dc.date.accessioned | 2021-09-17T07:42:27Z | - |
dc.date.available | 2021-09-17T07:42:27Z | - |
dc.date.issued | 2021 | - |
dc.date.submitted | 2021-09-16T09:30:48Z | - |
dc.identifier.citation | Journal of physical chemistry. C, 125 (33) , p. 18317 -18327 | - |
dc.identifier.uri | http://hdl.handle.net/1942/35398 | - |
dc.description.abstract | 2D hybrid perovskites consisting of layers of lead halide octahedra separated by long organic linker cations have great potential for functional material design toward tailored optical and electronic properties. Here, we report the first direct observation of light-induced charge transfer (CT) in a series of novel 2D perovskites incorporating conjugated linkers based on the carbazole molecule. Dedicated electron paramagnetic resonance experiments and supporting quantum-chemical calculations reveal that excitons generated in the lead halide layer undergo CT at the organic-inorganic interface, resulting in a positive polaron delocalized over several carbazole moieties and a partner electron residing in the inorganic layer. The occurrence of such CT processes in these materials not only offers interesting new perspectives for the functionalization of future 2D perovskites but could also lead to a better understanding of the unusual broadband emission reported for this material class, which has been directly related to polaronic effects. | - |
dc.description.sponsorship | Research Foundation Flanders (FWO.Vlaanderen)FWO [1185019N, S002019N, 1S17516N, G043320N]; M-ERA.NET project called PROMISES; Interreg Vlaanderen-Nederland | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.rights | © 2021 American Chemical Society | - |
dc.title | Light-Induced Charge Transfer in Two-Dimensional Hybrid Lead Halide Perovskites | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 18327 | - |
dc.identifier.issue | 33 | - |
dc.identifier.spage | 18317 | - |
dc.identifier.volume | 125 | - |
local.format.pages | 11 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | Goovaerts, E (corresponding author), Univ Antwerp, Dept Phys, B-2610 Antwerp, Belgium. | - |
dc.description.notes | etienne.goovaerts@uantwerpen.be | - |
local.publisher.place | 1155 16TH ST, NW, WASHINGTON, DC 20036 USA | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.identifier.doi | 10.1021/acs.jpcc.1c05005 | - |
dc.identifier.isi | WOS:000692021300026 | - |
local.provider.type | wosris | - |
local.uhasselt.uhpub | yes | - |
local.description.affiliation | [Van Landeghem, Melissa; Goovaerts, Etienne] Univ Antwerp, Dept Phys, B-2610 Antwerp, Belgium. | - |
local.description.affiliation | [Van Landeghem, Melissa] Hasselt Univ, Inst Mat Res IMO IMOMEC, Agoralaan 1, B-3590 Diepenbeek, Belgium. | - |
local.description.affiliation | [Van Gompel, Wouter; Herckens, Roald; Lutsen, Laurence; Vanderzande, Dirk] Hasselt Univ, Inst Mat Res IMO IMOMEC, Hybrid Mat Design HyMAD, B-3590 Diepenbeek, Belgium. | - |
local.description.affiliation | [Van Doorslaer, Sabine] Univ Antwerp, Dept Chem, B-2610 Antwerp, Belgium. | - |
local.uhasselt.international | no | - |
item.contributor | VAN LANDEGHEM, Melissa | - |
item.contributor | VAN GOMPEL, Wouter | - |
item.contributor | HERCKENS, Roald | - |
item.contributor | LUTSEN, Laurence | - |
item.contributor | VANDERZANDE, Dirk | - |
item.contributor | VAN DOORSLAER, Sabine | - |
item.contributor | Goovaerts, Etienne | - |
item.fulltext | With Fulltext | - |
item.validation | ecoom 2022 | - |
item.fullcitation | VAN LANDEGHEM, Melissa; VAN GOMPEL, Wouter; HERCKENS, Roald; LUTSEN, Laurence; VANDERZANDE, Dirk; VAN DOORSLAER, Sabine & Goovaerts, Etienne (2021) Light-Induced Charge Transfer in Two-Dimensional Hybrid Lead Halide Perovskites. In: Journal of physical chemistry. C, 125 (33) , p. 18317 -18327. | - |
item.accessRights | Restricted Access | - |
crisitem.journal.issn | 1932-7447 | - |
crisitem.journal.eissn | 1932-7455 | - |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
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acsjpcc1c05005.pdf Restricted Access | Published version | 2.02 MB | Adobe PDF | View/Open Request a copy |
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