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http://hdl.handle.net/1942/3568
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DC Field | Value | Language |
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dc.contributor.author | KIEBOOMS, Rafael | - |
dc.contributor.author | HOOGMARTENS, I | - |
dc.contributor.author | ADRIAENSENS, Peter | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.contributor.author | GELAN, Jan | - |
dc.date.accessioned | 2007-11-29T08:29:02Z | - |
dc.date.available | 2007-11-29T08:29:02Z | - |
dc.date.issued | 1995 | - |
dc.identifier.citation | MACROMOLECULES, 28(14). p. 4961-4969 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.uri | http://hdl.handle.net/1942/3568 | - |
dc.description.abstract | The simulation of the structure of aromatic and quinoid poly(isothianaphthene) (PITN) has been improved, by the synthesis of new model compounds. The C-13 NMR investigation confirms our previous results that the geometric structure of this low-band-gap conducting polymer shows a strong quinoid character. For the aromatic structure, 1,3-dithienylisothianaphthene and a series of disilylated isothianaphthene oligomers were synthesized. trans-3,3'-Bibenzo[c]thienylidene was prepared in order to model the quinoid structure. All these new model compounds simulate better neighboring S-atom effects, a structural feature which was not accounted for in the previously reported model compounds. | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | LOW-BAND-GAP CONJUGATED POLYMERS - IMPROVED MODEL COMPOUNDS FOR THE STRUCTURAL-ANALYSIS OF POLY(ISOTHIANAPHTHENE) | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 4969 | - |
dc.identifier.issue | 14 | - |
dc.identifier.spage | 4961 | - |
dc.identifier.volume | 28 | - |
local.format.pages | 9 | - |
dc.description.notes | LIMBURGS UNIV CENTRUM,DIV CHEM,INST MAT RES,B-3590 DIEPENBEEK,BELGIUM. | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1021/ma00118a025 | - |
dc.identifier.isi | A1995RH91600025 | - |
item.accessRights | Closed Access | - |
item.contributor | KIEBOOMS, Rafael | - |
item.contributor | HOOGMARTENS, I | - |
item.contributor | ADRIAENSENS, Peter | - |
item.contributor | VANDERZANDE, Dirk | - |
item.contributor | GELAN, Jan | - |
item.fulltext | No Fulltext | - |
item.fullcitation | KIEBOOMS, Rafael; HOOGMARTENS, I; ADRIAENSENS, Peter; VANDERZANDE, Dirk & GELAN, Jan (1995) LOW-BAND-GAP CONJUGATED POLYMERS - IMPROVED MODEL COMPOUNDS FOR THE STRUCTURAL-ANALYSIS OF POLY(ISOTHIANAPHTHENE). In: MACROMOLECULES, 28(14). p. 4961-4969. | - |
Appears in Collections: | Research publications |
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