Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/35760
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dc.contributor.authorMolina, Pau Martinez-
dc.contributor.authorMeulendijks, Nicole-
dc.contributor.authorXu, Man-
dc.contributor.authorVerheijen, Marcel A.-
dc.contributor.authorden Hartog, Tim-
dc.contributor.authorBUSKENS, Pascal-
dc.contributor.authorSastre, Francesc-
dc.date.accessioned2021-11-04T10:56:27Z-
dc.date.available2021-11-04T10:56:27Z-
dc.date.issued2021-
dc.date.submitted2021-10-28T14:10:04Z-
dc.identifier.citationCHEMCATCHEM, 13 (21) , p. 4507-4513-
dc.identifier.issn1867-3880-
dc.identifier.urihttp://hdl.handle.net/1942/35760-
dc.description.abstractSunlight-powered reduction of CO2 to fuels and chemicals is a promising strategy to close the carbon loop and facilitate the energy transition. In this research, we demonstrate that Au nanoparticles supported on TiO2 are an efficient plasmonic catalyst for the sunlight-powered reverse water-gas shift (rWGS) reaction. A maximum CO production rate of 429 mmol g(Au)(-1) h(-1) with a selectivity of 98 % and an apparent quantum efficiency of 4.7 % were achieved using mildly concentrated sunlight (1.44 W cm(-2) equals 14.4 sun). The CO production rate showed an exponential increase with increasing light intensity, suggesting that the process is mainly promoted by a photothermal effect. Thermal reference experiments with the same catalysts promoted CH4 formation, dropping the CO selectivity to 70 %. Thus, mildly concentrated sunlight can efficiently and selectively enhance the promotion of the rWGS reaction without using external heating.-
dc.description.sponsorshipEuropean Fund for Regional Development through the cross border collaborative Interreg V program Flanders-The Netherlands (project LUMEN); Belgian province of Limburg; Dutch province of Limburg; Dutch province of Noord-Brabant; Solliance P.M., N.M., M.X., T.H., P.B. and F.S. acknowledge financial support from the European Fund for Regional Development through the cross border collaborative Interreg V program Flanders-The Netherlands (project LUMEN), co-financed by the Belgian province of Limburg and the Dutch provinces of Limburg and NoordBrabant. M.A.V. acknowledges Solliance and the Dutch province of Noord-Brabant for funding the TEM facility. We thank Prof. dr. Wouter Marchal from the Hasselt University for the ICP analyse-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.rights2021 The Authors. ChemCatChem published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution-
dc.subject.otherCarbon Dioxide-
dc.subject.otherReverse Water-Gas Shift-
dc.subject.otherCO-
dc.subject.othersolar light-
dc.subject.otherSurface plasmon resonance-
dc.subject.otherPhotochemistry-
dc.titleLow Temperature Sunlight‐Powered Reduction of CO2 to CO Using a Plasmonic Au/TiO2 Nanocatalyst-
dc.typeJournal Contribution-
dc.identifier.epage4513-
dc.identifier.issue21-
dc.identifier.spage4507-
dc.identifier.volume13-
local.format.pages8-
local.bibliographicCitation.jcatA1-
dc.description.notesBuskens, P; Sastre, F (corresponding author), Netherlands Org Appl Sci Res TNO, High Tech Campus 25, NL-5656 AE Eindhoven, Netherlands.; Buskens, P (corresponding author), Hasselt Univ, Inst Mat Res Design & Synth Inorgan Mat DESINe, Agoralaan Bldg D, B-3590 Diepenbeek, Belgium.-
dc.description.notespascal.buskens@tno.nl; francesc.sastrecalabuig@tno.nl-
local.publisher.placePOSTFACH 101161, 69451 WEINHEIM, GERMANY-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1002/cctc.202100699-
dc.identifier.isi000697229200001-
dc.identifier.eissn1867-3899-
local.provider.typewosris-
local.uhasselt.uhpubyes-
local.description.affiliation[Molina, Pau Martinez; Meulendijks, Nicole; Xu, Man; den Hartog, Tim; Buskens, Pascal; Sastre, Francesc] Netherlands Org Appl Sci Res TNO, High Tech Campus 25, NL-5656 AE Eindhoven, Netherlands.-
local.description.affiliation[Xu, Man] Delft Univ Technol, Opt Res Grp, Lorentzweg 1,Bldg 22, NL-2628 CJ Delft, Netherlands.-
local.description.affiliation[Verheijen, Marcel A.] Eurofins Mat Sci, High Tech Campus 11, NL-5656 AE Eindhoven, Netherlands.-
local.description.affiliation[Verheijen, Marcel A.] Eindhoven Univ Technol, Dept Appl Phys, POB 513, NL-5600 MB Eindhoven, Netherlands.-
local.description.affiliation[den Hartog, Tim] Zuyd Univ Appl Sci, Nieuw Eyckholt 300, NL-6400 AN Heerlen, Netherlands.-
local.description.affiliation[Buskens, Pascal] Hasselt Univ, Inst Mat Res Design & Synth Inorgan Mat DESINe, Agoralaan Bldg D, B-3590 Diepenbeek, Belgium.-
local.uhasselt.internationalyes-
item.contributorMolina, Pau Martinez-
item.contributorMeulendijks, Nicole-
item.contributorXu, Man-
item.contributorVerheijen, Marcel A.-
item.contributorden Hartog, Tim-
item.contributorBUSKENS, Pascal-
item.contributorSastre, Francesc-
item.fulltextWith Fulltext-
item.validationecoom 2022-
item.fullcitationMolina, Pau Martinez; Meulendijks, Nicole; Xu, Man; Verheijen, Marcel A.; den Hartog, Tim; BUSKENS, Pascal & Sastre, Francesc (2021) Low Temperature Sunlight‐Powered Reduction of CO2 to CO Using a Plasmonic Au/TiO2 Nanocatalyst. In: CHEMCATCHEM, 13 (21) , p. 4507-4513.-
item.accessRightsOpen Access-
crisitem.journal.issn1867-3880-
crisitem.journal.eissn1867-3899-
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