Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3645
Title: A POTENTIOMETRIC STUDY OF THE COMPLEXATION OF ALIPHATIC ACYCLIC MONOAMINES WITH AG(I) IN 1 M NITRATE
Authors: GARNER, R
YPERMAN, Jan 
MULLENS, Jules 
VAN POUCKE, Lucien 
Issue Date: 1993
Publisher: GORDON BREACH SCI PUBL LTD
Source: JOURNAL OF COORDINATION CHEMISTRY, 30(2). p. 151-164
Abstract: Complexation of 12 aliphatic monoamines with Ag(I) has been studied in IM KNO3 at 25-degrees-C using a potentiometric titration technique, performing pH and pAg measurements. To study these ternary systems, the binary systems (Ag-OH, LH, H-OH) were first investigated. The model used for background Ag(I) hydrolysis is consistent with the literature. Graphical techniques were used for the calculation of formation constants of silver-amine complexes. The estimates were further refined using the Superquad program. Evidence has been found for the formation of mixed Ag(I)-hydroxo ligand complexes only with aliphatic primary monoamines.
Notes: LIMBURGS UNIV CENTRUM,INORGAN & PHYS CHEM LAB,B-3590 DIEPENBEEK,BELGIUM.
Keywords: ALIPHATIC MONOAMINES; SILVER; COMPLEXES; HYDROLYSIS; MIXED COMPLEXES; STABILITY CONSTANTS
Document URI: http://hdl.handle.net/1942/3645
ISI #: A1993MP03500006
Type: Journal Contribution
Appears in Collections:Research publications

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