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Title: | A potentiometric study of the complexation of aliphatic acyclic monoamines with Ag(I) in 1 M nitrate | Authors: | GARNER, R YPERMAN, Jan MULLENS, Jules VAN POUCKE, Lucien |
Issue Date: | 1993 | Publisher: | GORDON BREACH SCI PUBL LTD | Source: | JOURNAL OF COORDINATION CHEMISTRY, 30(2). p. 151-164 | Abstract: | Complexation of 12 aliphatic monoamines with Ag(I) has been studied in IM KNO3 at 25-degrees-C using a potentiometric titration technique, performing pH and pAg measurements. To study these ternary systems, the binary systems (Ag-OH, LH, H-OH) were first investigated. The model used for background Ag(I) hydrolysis is consistent with the literature. Graphical techniques were used for the calculation of formation constants of silver-amine complexes. The estimates were further refined using the Superquad program. Evidence has been found for the formation of mixed Ag(I)-hydroxo ligand complexes only with aliphatic primary monoamines. | Notes: | LIMBURGS UNIV CENTRUM,INORGAN & PHYS CHEM LAB,B-3590 DIEPENBEEK,BELGIUM. | Keywords: | ALIPHATIC MONOAMINES; SILVER; COMPLEXES; HYDROLYSIS; MIXED COMPLEXES; STABILITY CONSTANTS | Document URI: | http://hdl.handle.net/1942/3645 | ISI #: | A1993MP03500006 | Type: | Journal Contribution |
Appears in Collections: | Research publications |
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