Please use this identifier to cite or link to this item:
http://hdl.handle.net/1942/3739
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | GARNER, R | - |
dc.contributor.author | YPERMAN, Jan | - |
dc.contributor.author | MULLENS, Jules | - |
dc.contributor.author | VAN POUCKE, Lucien | - |
dc.date.accessioned | 2007-11-29T13:00:33Z | - |
dc.date.available | 2007-11-29T13:00:33Z | - |
dc.date.issued | 1994 | - |
dc.identifier.citation | INORGANICA CHIMICA ACTA, 224(1-2). p. 97-104 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.uri | http://hdl.handle.net/1942/3739 | - |
dc.description.abstract | The complexation of Ag(I) with five different N-methyl substituted, two C-methyl substituted ethylenediamines and ethylenediamine itself is studied using potentiometric pH and pAg measurements in 1 M KNO3 at 25.0-degrees-C. Mononuclear complexes, polynuclear complexes and their protonated forms are detected and the respective stability constants are tabulated. The stability constant of a given species generally decreases as the methylation increases on the terminal amino groups probably due to an increased steric hindrance. The number of species also decreases as the methylation increases. The stability constants of the ethylenediamines are also compared with previously determined stability constants of Ag(I)-propylenediamine complexes and some relationships are identified. | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA LAUSANNE | - |
dc.subject.other | POTENTIOMETRIC TITRATION; STABILITY CONSTANTS; SILVER COMPLEXES; DIAMINE COMPLEXES | - |
dc.title | A POTENTIOMETRIC STUDY ON THE COMPLEXATION OF AG(I) WITH VARIOUS N-METHYL AND C-METHYL SUBSTITUTED ETHYLENEDIAMINES IN 1-M NO3- | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 104 | - |
dc.identifier.issue | 1-2 | - |
dc.identifier.spage | 97 | - |
dc.identifier.volume | 224 | - |
local.format.pages | 8 | - |
dc.description.notes | GARNER, R, LIMBURGS UNIV CTR,INORGAN & PHYS CHEM LAB,B-3590 DIEPENBEEK,BELGIUM. | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.isi | A1994PH02200012 | - |
item.fulltext | No Fulltext | - |
item.fullcitation | GARNER, R; YPERMAN, Jan; MULLENS, Jules & VAN POUCKE, Lucien (1994) A POTENTIOMETRIC STUDY ON THE COMPLEXATION OF AG(I) WITH VARIOUS N-METHYL AND C-METHYL SUBSTITUTED ETHYLENEDIAMINES IN 1-M NO3-. In: INORGANICA CHIMICA ACTA, 224(1-2). p. 97-104. | - |
item.accessRights | Closed Access | - |
item.contributor | GARNER, R | - |
item.contributor | YPERMAN, Jan | - |
item.contributor | MULLENS, Jules | - |
item.contributor | VAN POUCKE, Lucien | - |
Appears in Collections: | Research publications |
WEB OF SCIENCETM
Citations
3
checked on May 10, 2024
Page view(s)
84
checked on Aug 6, 2023
Google ScholarTM
Check
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.