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http://hdl.handle.net/1942/3791
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | GARNER, R | - |
dc.contributor.author | YPERMAN, Jan | - |
dc.contributor.author | MULLENS, Jules | - |
dc.contributor.author | VAN POUCKE, Lucien | - |
dc.date.accessioned | 2007-11-29T13:39:41Z | - |
dc.date.available | 2007-11-29T13:39:41Z | - |
dc.date.issued | 1994 | - |
dc.identifier.citation | JOURNAL OF COORDINATION CHEMISTRY, 31(2). p. 117-123 | - |
dc.identifier.issn | 0095-8972 | - |
dc.identifier.uri | http://hdl.handle.net/1942/3791 | - |
dc.description.abstract | The complexation behaviour of a number of N-methylpropylene diamines with Ag(I) were studied in 1 M KNO3 at 25.00-degrees-C potentiometrically, employing pH and pAg measurements. Several metal/ligand ratios were used (varying from 2/1 to 1/8). Complexation of these ligands with Ag(I) in aqueous solution is described by the following species: AgL, AgLH, AgL2, AgL2H, AgL2H2, Ag2L2 and Ag2L2H. No mixed ligand hydroxo species could be detected in the concentration employed. Stability constants of a given species systematically decrease as methylation increases on the terminal amino groups due to increased steric effects. | - |
dc.language.iso | en | - |
dc.publisher | GORDON BREACH SCI PUBL LTD | - |
dc.subject.other | N-METHYLPROPYLNEDIAMINES; ALIPHATIC DIAMINES; SILVER STABILITY CONSTANTS | - |
dc.title | AG(I)-N-METHYLSUBSTITUTED 1,3-DIAMINOPROPANE COMPLEXES IN 1-M NO3- | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 123 | - |
dc.identifier.issue | 2 | - |
dc.identifier.spage | 117 | - |
dc.identifier.volume | 31 | - |
local.format.pages | 7 | - |
dc.description.notes | LIMBURGS UNIV CENTRUM,INORGAN & PHYS CHEM LAB,B-3590 DIEPENBEEK,BELGIUM. | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.isi | A1994NM52600004 | - |
item.accessRights | Closed Access | - |
item.fulltext | No Fulltext | - |
item.contributor | GARNER, R | - |
item.contributor | YPERMAN, Jan | - |
item.contributor | MULLENS, Jules | - |
item.contributor | VAN POUCKE, Lucien | - |
item.fullcitation | GARNER, R; YPERMAN, Jan; MULLENS, Jules & VAN POUCKE, Lucien (1994) AG(I)-N-METHYLSUBSTITUTED 1,3-DIAMINOPROPANE COMPLEXES IN 1-M NO3-. In: JOURNAL OF COORDINATION CHEMISTRY, 31(2). p. 117-123. | - |
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