Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/40214
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dc.contributor.authorVERCRUYSSE, Willem-
dc.contributor.authorGomes, Caio Laurino-
dc.contributor.authorBLEUS, Dries-
dc.contributor.authorPAPPA, Michaela-
dc.contributor.authorJOOS, Bjorn-
dc.contributor.authorHARDY, An-
dc.contributor.authorMARCHAL, Wouter-
dc.contributor.authorVANDAMME, Dries-
dc.date.accessioned2023-05-30T14:57:15Z-
dc.date.available2023-05-30T14:57:15Z-
dc.date.issued2023-
dc.date.submitted2023-05-22T07:21:48Z-
dc.identifier.citationSEPARATION AND PURIFICATION TECHNOLOGY, 319 (Art N° 124023)-
dc.identifier.issn1383-5866-
dc.identifier.urihttp://hdl.handle.net/1942/40214-
dc.description.abstractBiomass waste often contains high amounts of inorganic impurities, which is a limitation for developing high-quality bioproducts, e.g., high-purity activated carbons (ACs). Otherwise, these would be applicable to purify polluted water and air streams. Conventionally, AC’s are purified with non-sustainable and corrosive inorganic acids. This study illustrates the successful removal of the impurities from common ivy, Hedera helix L., through treatment with a natural deep eutectic solvent (NADES), namely choline chloride-malic acid (CCl:MA, 1:1 M). The demineralization efficiency is benchmarked against H2O and dilute hydrochloric acid (HCl). Moreover, the importance of the process sequence, pre- or post- pyrolysis demineralization, for AC-production was investigated. The three solvents showed different biomass (pre-pyrolysis) demineralization efficiencies, they were ranked, from best to worst, as follows: HCl > CCl:MA > H2O. However, demineralizing the biomass after pyrolysis yielded highly porous ACs, with a good mix of meso-and micropores. In this case, no differences in removal performance could be observed between HCl and CCl:MA. Lastly, the ACs phosphate adsorption capacity was highest after demineralizing biomass with either H2O or CCl:MA. Ultimately, this investigation demonstrated CCl:MA’s potential as a green demineralization agent to treat metal-contaminated biomass in future bio-refinery processes.-
dc.description.sponsorshipThis work was financially supported by Research Foundation Flanders (FWO – SB-1S92022N).-
dc.language.isoen-
dc.publisher-
dc.rightsElsevier-
dc.subject.otherCommon Ivy-
dc.subject.otherDemineralization-
dc.subject.otherBiochar-
dc.subject.otherNatural deep-eutectic solvents-
dc.subject.otherActivated carbon-
dc.titleDemineralization of common ivy-derived biomass and biochar and its effect on the resulting activated carbon properties-
dc.typeJournal Contribution-
dc.identifier.volume319-
local.bibliographicCitation.jcatA1-
local.publisher.placeRADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS-
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local.type.refereedRefereed-
local.type.specifiedArticle-
local.bibliographicCitation.artnr124023-
dc.identifier.doi10.1016/j.seppur.2023.124023-
dc.identifier.isi001012881500001-
dc.identifier.eissn1873-3794-
local.provider.typePdf-
local.uhasselt.internationalyes-
item.validationecoom 2024-
item.contributorVERCRUYSSE, Willem-
item.contributorGomes, Caio Laurino-
item.contributorBLEUS, Dries-
item.contributorPAPPA, Michaela-
item.contributorJOOS, Bjorn-
item.contributorHARDY, An-
item.contributorMARCHAL, Wouter-
item.contributorVANDAMME, Dries-
item.fullcitationVERCRUYSSE, Willem; Gomes, Caio Laurino; BLEUS, Dries; PAPPA, Michaela; JOOS, Bjorn; HARDY, An; MARCHAL, Wouter & VANDAMME, Dries (2023) Demineralization of common ivy-derived biomass and biochar and its effect on the resulting activated carbon properties. In: SEPARATION AND PURIFICATION TECHNOLOGY, 319 (Art N° 124023).-
item.embargoEndDate2025-08-15-
item.fulltextWith Fulltext-
item.accessRightsEmbargoed Access-
crisitem.journal.issn1383-5866-
crisitem.journal.eissn1873-3794-
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