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Title: | Functionalization of Carbon Surfaces Using the Copper-Catalyzed Diels-Alder Reaction | Authors: | Ari, Denis Bergamini, Jean-Francois Rodrigues, Teresa Knoll, Wolfgang Cougnon, Charles AHMED, Essraa POBEDINSKAS, Paulius HAENEN, Ken Nuns, Nicolas Boukherroub, Rabah Szunerits, Sabine Leroux, Yann R. |
Issue Date: | 2023 | Publisher: | AMER CHEMICAL SOC | Source: | CHEMISTRY OF MATERIALS, 35 (13) , p. 4935 -4944 | Abstract: | We propose here a new method to functionalize carbonmaterials via a catalyzed Diels-Alder reaction.In a Diels-Alderreaction, carbon materials can be used as a diene or a dienophile.Here, carbon materials are used as dienes and alkyne-terminated derivativesas dienophiles. Different carbon materials, i.e., glassy carbon, carbonpowder (carbon black), pyrolytic graphite carbon materials, and graphene,were functionalized by alkyne ferrocene derivatives or perfluoro-taggedalkyne molecules and characterized by electrochemical means, atomicforce microscopy, and X-ray photoelectron spectroscopy experiments.This method allows for the rapid functionalization of carbon materialsin mild conditions with high surface coverage. | Notes: | Leroux, YR (corresponding author), Univ Rennes, CNRS, ISCR UMR 6226, F-35000 Rennes, France.; Szunerits, S (corresponding author), Univ Lille, CNRS, Cent Lille, Univ Polytech Hauts de France,UMR 8520,IEMN, F-59000 Lille, France.; Szunerits, S (corresponding author), Danube Private Univ, Fac Med & Dent, Lab Life Sci & Technol LiST, A-3500 Krems, Austria. sabine.szunerits@univ-lille.fr; yann.leroux@univ-rennes1.fr |
Document URI: | http://hdl.handle.net/1942/40706 | ISSN: | 0897-4756 | e-ISSN: | 1520-5002 | DOI: | 10.1021/acs.chemmater.3c00055 | ISI #: | 001018201300001 | Rights: | 2023 American Chemical Society | Category: | A1 | Type: | Journal Contribution |
Appears in Collections: | Research publications |
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Functionalization of Carbon Surfaces Using the Copper-Catalyzed Diels–Alder Reaction.pdf Restricted Access | Published version | 4.27 MB | Adobe PDF | View/Open Request a copy |
Functionalization of Carbon.pdf | Peer-reviewed author version | 6.26 MB | Adobe PDF | View/Open |
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