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http://hdl.handle.net/1942/4157
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DC Field | Value | Language |
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dc.contributor.author | BANISHOEIB, Fateme | - |
dc.contributor.author | ADRIAENSENS, Peter | - |
dc.contributor.author | Berson, Solenn | - |
dc.contributor.author | Guillerez, S. | - |
dc.contributor.author | DOUHERET, Olivier | - |
dc.contributor.author | MANCA, Jean | - |
dc.contributor.author | FOURIER, Sofie | - |
dc.contributor.author | CLEIJ, Thomas | - |
dc.contributor.author | LUTSEN, Laurence | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.date.accessioned | 2007-12-11T09:11:22Z | - |
dc.date.available | 2007-12-11T09:11:22Z | - |
dc.date.issued | 2007 | - |
dc.identifier.citation | SOLAR ENERGY MATERIALS AND SOLAR CELLS, 91(11). p. 1026-1034 | - |
dc.identifier.issn | 0927-0248 | - |
dc.identifier.uri | http://hdl.handle.net/1942/4157 | - |
dc.description.abstract | Poly(2,5-thienylene vinylene) derivatives (PTVs) present a specific class of low band gap conjugated polymers of which the synthesis seems to be problematic. Recently, the dithiocarbamate route was introduced as a synthetic route towards PTV. However, the synthesis of alkyl-PTV derivatives failed on using lithium diisopropyl amide (LDA) as the base in the polymerisation reaction. We demonstrate that the use of lithium bis(trimethylsilyl)amide (LHMDS) instead of LDA allows for an efficient synthesis of alkyl-PTV derivatives. Indications are presented for the formation of an ordered structure in case of the 3-alkyl derivative, pointing to a regio-regular polymerisation process. (c) 2007 Elsevier B.V. All rights reserved. | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.subject.other | low band gap; conjugated polymer; precursor polymer; PTV | - |
dc.title | The synthesis of regio-regular poly(3-alkyl-2,5-thienylene vinylene) derivatives using lithium bis(trimethylsilyl)amide (LHMDS) in the dithiocarbamate precursor | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 1034 | - |
dc.identifier.issue | 11 | - |
dc.identifier.spage | 1026 | - |
dc.identifier.volume | 91 | - |
local.format.pages | 9 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | Hasselt Univ, Inst Mat Res, B-3590 Diepenbeek, Belgium. IMEC, IMOMEC Div, B-3590 Diepenbeek, Belgium. CEA, DRFMC, SPrAM, LEMOH,UMR 5819, F-38054 Grenoble, France.VANDERZANDE, D, Hasselt Univ, Inst Mat Res, Bldg D, B-3590 Diepenbeek, Belgium.dirk.vanderzande@uhasselt.be | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1016/j.solmat.2007.02.013 | - |
dc.identifier.isi | 000246671600007 | - |
item.fullcitation | BANISHOEIB, Fateme; ADRIAENSENS, Peter; Berson, Solenn; Guillerez, S.; DOUHERET, Olivier; MANCA, Jean; FOURIER, Sofie; CLEIJ, Thomas; LUTSEN, Laurence & VANDERZANDE, Dirk (2007) The synthesis of regio-regular poly(3-alkyl-2,5-thienylene vinylene) derivatives using lithium bis(trimethylsilyl)amide (LHMDS) in the dithiocarbamate precursor. In: SOLAR ENERGY MATERIALS AND SOLAR CELLS, 91(11). p. 1026-1034. | - |
item.accessRights | Closed Access | - |
item.fulltext | No Fulltext | - |
item.contributor | BANISHOEIB, Fateme | - |
item.contributor | ADRIAENSENS, Peter | - |
item.contributor | Berson, Solenn | - |
item.contributor | Guillerez, S. | - |
item.contributor | DOUHERET, Olivier | - |
item.contributor | MANCA, Jean | - |
item.contributor | FOURIER, Sofie | - |
item.contributor | CLEIJ, Thomas | - |
item.contributor | LUTSEN, Laurence | - |
item.contributor | VANDERZANDE, Dirk | - |
item.validation | ecoom 2008 | - |
crisitem.journal.issn | 0927-0248 | - |
crisitem.journal.eissn | 1879-3398 | - |
Appears in Collections: | Research publications |
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