Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/41638
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dc.contributor.authorSebastia-Luna, Paz-
dc.contributor.authorRodkey, Nathan-
dc.contributor.authorMirza, Adeem Saeed-
dc.contributor.authorMERTENS, Sigurd-
dc.contributor.authorLal, Snigdha-
dc.contributor.authorCarranza, Axel Melchor Gaona-
dc.contributor.authorCalbo, Joaquin-
dc.contributor.authorRighetto, Marcello-
dc.contributor.authorSessolo, Michele-
dc.contributor.authorHerz, Laura M.-
dc.contributor.authorVANDEWAL, Koen-
dc.contributor.authorOrti, Enrique-
dc.contributor.authorMorales-Masis, Monica-
dc.contributor.authorBolink, Henk J.-
dc.contributor.authorPalazon, Francisco-
dc.date.accessioned2023-10-27T11:11:36Z-
dc.date.available2023-10-27T11:11:36Z-
dc.date.issued2023-
dc.date.submitted2023-10-26T18:07:22Z-
dc.identifier.citationCHEMISTRY OF MATERIALS, 35 (16) , p. 6482 -6490-
dc.identifier.urihttp://hdl.handle.net/1942/41638-
dc.description.abstractSilver chalcohalide antiperovskites represent a ratherunexploredalternative to lead halide perovskites and other semiconductors basedon toxic heavy metals. All synthetic approaches reported so far forAg(3)SI and Ag3SBr require long synthesis times(typically days, weeks, or even months) and high temperatures. Herein,we report the synthesis of these materials using a fast and low-temperaturemethod involving mechanochemistry. Structural and optical propertiesare examined experimentally and supported by first-principles calculations.Furthermore, we deposit Ag3SI as thin films by pulsed laserdeposition and characterize its optoelectronic properties using optical-pump-terahertz-probemeasurements, revealing a high charge-carrier mobility of 49 cm(2) V-1 s(-1). This work pavesthe way to the implementation of chalcohalide antiperovskites in variousoptoelectronic applications.-
dc.description.sponsorshipThe research leading to these results has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement no. 834431). The authors acknowledge support from the Comunitat Valenciana (IDIFEDER/2018/ 061, GV/2021/027, PROMETEU/2020/077, and CISEJI/ 2022/43), as well as by the Ministry of Science and Innovation (MCIN) and the Spanish State Research Agency (AEI) (projects PID2020-119748GA-I00, PID2021-128569NB-I00, and CEX2019-000919-M, funded by MCIN/AEI/10.13039/ 501100011033 and by “ERDF A way of making Europe”, project TED2021-131255B−C44 funded by MCIN/AEI/ 10.13039/501100011033 and by European Union NextGenerationEU/PRTR, grants RYC-2016-21316 and RYC2020- 028803-I funded by MCIN/AEI/10.13039/501100011033 and “ESF Investing in your future”). Dutch Research Council (NWO, FOM Focus Group “Next Generation Organic Photovoltaics”). P.S. thanks the Spanish Ministry of Universities for her predoctoral grant (FPU18/01732 and EST19/ 00295). A.S.M. and M.M.M. acknowledge the financial support of the NWO StartUp 2019 project BRIDGE (project number: STU.019.026). M.R. and L.M.H. acknowledge financial support from the Engineering and Physical Sciences Research Council U.K. S.L. acknowledges funding from the Oxford India Centre for Sustainable Development. F.P. thanks Dr. Quinten A. Akkerman for first telling him about these materials in 2019 in a conversation that sparked the research leading to the results presented herein.-
dc.language.isoen-
dc.publisherAMER CHEMICAL SOC-
dc.rights2023 American Chemical Society 6-
dc.titleChalcohalide Antiperovskite Thin Films with Visible Light Absorption and High Charge-Carrier Mobility Processed by Solvent-Free and Low-Temperature Methods-
dc.typeJournal Contribution-
dc.identifier.epage6490-
dc.identifier.issue16-
dc.identifier.spage6482-
dc.identifier.volume35-
local.format.pages9-
local.bibliographicCitation.jcatA1-
dc.description.notesBolink, HJ; Palazon, F (corresponding author), Univ Valencia, Inst Ciencia Mol, Paterna 46980, Spain.; Palazon, F (corresponding author), Univ Politecn Cartagena, Dept Ingn Quim & Ambiental, Cartagena 30202, Spain.-
dc.description.noteshenk.bolink@uv.es; francisco.palazon@upct.es-
local.publisher.place1155 16TH ST, NW, WASHINGTON, DC 20036 USA-
local.type.refereedRefereed-
local.type.specifiedArticle-
local.type.programmeH2020-
local.relation.h2020834431-
dc.identifier.doi10.1021/acs.chemmater.3c01349-
dc.identifier.isi001044544900001-
dc.contributor.orcidHerz, Laura/0000-0001-9621-334X; Sebastia Luna, Paz/0000-0001-6992-199X;-
dc.contributor.orcidGaona, Axel/0000-0001-5911-1512; Calbo, Joaquin/0000-0003-4729-0757;-
dc.contributor.orcidLal, Snigdha/0000-0002-3086-1990; Righetto,-
dc.contributor.orcidMarcello/0000-0001-5507-1445; Sessolo, Michele/0000-0002-9189-3005;-
dc.contributor.orcidRodkey, Nathan/0000-0003-4246-3911-
local.provider.typewosris-
local.description.affiliation[Sebastia-Luna, Paz; Rodkey, Nathan; Carranza, Axel Melchor Gaona; Calbo, Joaquin; Sessolo, Michele; Orti, Enrique; Bolink, Henk J.; Palazon, Francisco] Univ Valencia, Inst Ciencia Mol, Paterna 46980, Spain.-
local.description.affiliation[Rodkey, Nathan; Mirza, Adeem Saeed; Morales-Masis, Monica] Univ Twente, MESA Inst Nanotechnol, NL-7500 AE Enschede, Netherlands.-
local.description.affiliation[Mertens, Sigurd; Vandewal, Koen] Hasselt Univ, Inst Mat Res, IMO, IMOMEC, B-3590 Diepenbeek, Belgium.-
local.description.affiliation[Lal, Snigdha; Righetto, Marcello; Herz, Laura M.] Univ Oxford, Dept Phys, Clarendon Lab, Oxford OX1 3PU, England.-
local.description.affiliation[Herz, Laura M.] Tech Univ Munich, Inst Adv Study, D-85748 Garching, Germany.-
local.description.affiliation[Palazon, Francisco] Univ Politecn Cartagena, Dept Ingn Quim & Ambiental, Cartagena 30202, Spain.-
local.uhasselt.internationalyes-
item.fullcitationSebastia-Luna, Paz; Rodkey, Nathan; Mirza, Adeem Saeed; MERTENS, Sigurd; Lal, Snigdha; Carranza, Axel Melchor Gaona; Calbo, Joaquin; Righetto, Marcello; Sessolo, Michele; Herz, Laura M.; VANDEWAL, Koen; Orti, Enrique; Morales-Masis, Monica; Bolink, Henk J. & Palazon, Francisco (2023) Chalcohalide Antiperovskite Thin Films with Visible Light Absorption and High Charge-Carrier Mobility Processed by Solvent-Free and Low-Temperature Methods. In: CHEMISTRY OF MATERIALS, 35 (16) , p. 6482 -6490.-
item.fulltextWith Fulltext-
item.contributorSebastia-Luna, Paz-
item.contributorRodkey, Nathan-
item.contributorMirza, Adeem Saeed-
item.contributorMERTENS, Sigurd-
item.contributorLal, Snigdha-
item.contributorCarranza, Axel Melchor Gaona-
item.contributorCalbo, Joaquin-
item.contributorRighetto, Marcello-
item.contributorSessolo, Michele-
item.contributorHerz, Laura M.-
item.contributorVANDEWAL, Koen-
item.contributorOrti, Enrique-
item.contributorMorales-Masis, Monica-
item.contributorBolink, Henk J.-
item.contributorPalazon, Francisco-
item.accessRightsOpen Access-
crisitem.journal.issn0897-4756-
crisitem.journal.eissn1520-5002-
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