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http://hdl.handle.net/1942/42267
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DC Field | Value | Language |
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dc.contributor.author | TUTUNDZIC, Merve | - |
dc.contributor.author | XIN, Zhang | - |
dc.contributor.author | LAMMAR, Stijn | - |
dc.contributor.author | Singh, Shivam | - |
dc.contributor.author | Marchezi, Paulo | - |
dc.contributor.author | MERCKX, Tamara | - |
dc.contributor.author | AGUIRRE, Aranzazu | - |
dc.contributor.author | Moons , Ellen | - |
dc.contributor.author | AERNOUTS, Tom | - |
dc.contributor.author | KUANG, Yinghuan | - |
dc.contributor.author | VERMANG, Bart | - |
dc.date.accessioned | 2024-01-29T12:11:21Z | - |
dc.date.available | 2024-01-29T12:11:21Z | - |
dc.date.issued | 2023 | - |
dc.date.submitted | 2024-01-29T11:08:39Z | - |
dc.identifier.citation | Solar RRL, 8 (3) (Art N° 202300862) | - |
dc.identifier.uri | http://hdl.handle.net/1942/42267 | - |
dc.description.abstract | Sputtered nickel oxide (NiOx ) has become one of the most promising inorganic hole transport layers for p-i-n perovskite solar cells (PSCs) due to its appealing features such as its robust nature, low material cost, and easy integration to tandem structures and large-area applications. However, the main drawback with NiOx -based PSCs is typically low open-circuit voltage ( V-OC ) due to the inferior energy-level alignment, low charge mobility, and high recombination at the interface. Herein , two types of phosphonic acid self-assembled monolayers (SAMs) deposited by blade coating as an interfacial layer to modulate the sputtered NiOx /perovskite interface properties are used. While sputtered NiOx serves as a conformally coated hole selective layer, the ultrathin SAM interlayer facilitates the hole extraction and minimizes the energy loss at the interface. Co-ordinately introduced stabilizing additive, namely octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate (I-76), further improves the device performance of NiOx/SAM-based PSCs, resulting in V-OC of 1.14 V and a power conversion efficiency of 21.8%. By applying these strategies for perovskite module upscaling, aperture area module efficiencies of 19.7%, 17.5%, and 15.5% for perovskite minimodules of 4, 16, and 100 cm(2) are demonstrated, corresponding to active area module efficiencies of 20.4%, 18.0%, and 16.4%, respectively. | - |
dc.description.sponsorship | This work was supported by the European Union’s Horizon 2020 research and innovation programme under grant agreement no. 850937 (PERCISTAND) and the FLAG-ERA JTC 2019 LASERGRAPH project (reference no.: JTC-2019-013). The authors would like to thank Karim Elkhouly at KU Leuven/imec for his contributions in external quantum efficiency electroluminescence measurements, Daniely Santos at Hasselt University/imec for her help in XRD measurements, Jan D’Haen at Hasselt University for his work in SEM measurements, and Wouter Van Gompel at Hasselt University for his assistance with contact angle measurements. | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.rights | 2023 Wiley-VCH GmbH | - |
dc.subject.other | additives | - |
dc.subject.other | blade coating | - |
dc.subject.other | Me-4PACz | - |
dc.subject.other | perovskite solar modules | - |
dc.subject.other | p-i-n perovskite solar cells | - |
dc.subject.other | self-assembled monolayers | - |
dc.subject.other | sputtered nickel oxides | - |
dc.title | Toward Efficient and Fully Scalable Sputtered NiOx-Based Inverted Perovskite Solar Modules via Co-Ordinated Modification Strategies | - |
dc.type | Journal Contribution | - |
dc.identifier.issue | 3 | - |
dc.identifier.volume | 8 | - |
local.format.pages | 12 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | Kuang, YH (corresponding author), Hasselt Univ, Imo Imomec, Martelarenlaan 42, B-3500 Hasselt, Belgium.; Kuang, YH (corresponding author), Imec, Imo Imomec, Thin Film PV Technol partner Solliance, Thor Pk 8320, B-3600 Genk, Belgium.; Kuang, YH (corresponding author), Imo Imomec, EnergyVille, Thor Pk 8320, B-3600 Genk, Belgium. | - |
dc.description.notes | yinghuan.kuang@imec.be | - |
local.publisher.place | POSTFACH 101161, 69451 WEINHEIM, GERMANY | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
local.bibliographicCitation.artnr | 202300862 | - |
local.type.programme | H2020 | - |
local.relation.h2020 | 850937 | - |
dc.identifier.doi | 10.1002/solr.202300862 | - |
dc.identifier.isi | 001133660600001 | - |
dc.contributor.orcid | Marchezi, Paulo Ernesto/0000-0002-7866-5411 | - |
local.provider.type | wosris | - |
local.description.affiliation | [Tutundzic, Merve; Merckx, Tamara; Aguirre, Aranzazu; Aernouts, Tom; Kuang, Yinghuan; Vermang, Bart] Hasselt Univ, Imo Imomec, Martelarenlaan 42, B-3500 Hasselt, Belgium. | - |
local.description.affiliation | [Tutundzic, Merve; Zhang, Xin; Lammar, Stijn; Merckx, Tamara; Aguirre, Aranzazu; Aernouts, Tom; Kuang, Yinghuan; Vermang, Bart] Imec, Imo Imomec, Thin Film PV Technol partner Solliance, Thor Pk 8320, B-3600 Genk, Belgium. | - |
local.description.affiliation | [Tutundzic, Merve; Zhang, Xin; Lammar, Stijn; Merckx, Tamara; Aguirre, Aranzazu; Aernouts, Tom; Kuang, Yinghuan; Vermang, Bart] Imo Imomec, EnergyVille, Thor Pk 8320, B-3600 Genk, Belgium. | - |
local.description.affiliation | [Zhang, Xin; Lammar, Stijn] Katholieke Univ Leuven, ESAT, B-3001 Heverlee, Belgium. | - |
local.description.affiliation | [Zhang, Xin] Fudan Univ, Ctr Micro Nano Syst, Sch Informat Sci & Technol SIST, Shanghai 200433, Peoples R China. | - |
local.description.affiliation | [Zhang, Xin] Fudan Univ, Acad Engn & Technol FAET, Shanghai 200433, Peoples R China. | - |
local.description.affiliation | [Singh, Shivam; Marchezi, Paulo; Moons, Ellen] Karlstad Univ, Dept Engn & Phys, SE-65188 Karlstad, Sweden. | - |
local.uhasselt.international | yes | - |
item.fulltext | With Fulltext | - |
item.fullcitation | TUTUNDZIC, Merve; XIN, Zhang; LAMMAR, Stijn; Singh, Shivam; Marchezi, Paulo; MERCKX, Tamara; AGUIRRE, Aranzazu; Moons , Ellen; AERNOUTS, Tom; KUANG, Yinghuan & VERMANG, Bart (2023) Toward Efficient and Fully Scalable Sputtered NiOx-Based Inverted Perovskite Solar Modules via Co-Ordinated Modification Strategies. In: Solar RRL, 8 (3) (Art N° 202300862). | - |
item.contributor | TUTUNDZIC, Merve | - |
item.contributor | XIN, Zhang | - |
item.contributor | LAMMAR, Stijn | - |
item.contributor | Singh, Shivam | - |
item.contributor | Marchezi, Paulo | - |
item.contributor | MERCKX, Tamara | - |
item.contributor | AGUIRRE, Aranzazu | - |
item.contributor | Moons , Ellen | - |
item.contributor | AERNOUTS, Tom | - |
item.contributor | KUANG, Yinghuan | - |
item.contributor | VERMANG, Bart | - |
item.accessRights | Restricted Access | - |
crisitem.journal.issn | 2367-198X | - |
crisitem.journal.eissn | 2367-198X | - |
Appears in Collections: | Research publications |
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File | Description | Size | Format | |
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Toward Efficient and Fully Scalable Sputtered NiOx‐Based Inverted.pdf Restricted Access | Published version | 6.4 MB | Adobe PDF | View/Open Request a copy |
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