Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/49234
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dc.contributor.authorRuser, Niklas-
dc.contributor.authorBehrens, Vanessa-
dc.contributor.authorMeier, Christoph-
dc.contributor.authorTHEISSEN, Jennifer-
dc.contributor.authorSteinke, Felix-
dc.contributor.authorNather, Christian-
dc.contributor.authorGosch, Jonas-
dc.contributor.authorStock, Norbert-
dc.date.accessioned2026-06-09T08:39:12Z-
dc.date.available2026-06-09T08:39:12Z-
dc.date.issued2026-
dc.date.submitted2026-06-08T07:39:02Z-
dc.identifier.citationZeitschrift Fur Anorganische Und Allgemeine Chemie,-
dc.identifier.urihttp://hdl.handle.net/1942/49234-
dc.description.abstractWe report the synthesis and crystal structure of anhydrous cerium(III) acetate [Ce(CH3COO)3] (1) as well as the interconversions to different hydrated phases. The structure determination of 1 was achieved by Rietveld refinement against powder X-ray diffraction (PXRD). Additionally, the thermal properties of 1 were investigated by thermogravimetry (TG) and variable-temperature PXRD (VT-PXRD) and a complete characterization was performed. 1 was prepared by solvothermal treatment of the sesquihydrate [Ce2(CH3COO)6(H2O)2]& centerdot;H2O (3). The dehydration is reversible and 1 can be transformed back to 3. Using VT-PXRD the transformation of 3 to 1 was studied. The step-wise dehydration does not proceed through [Ce(CH3COO)3(H2O)] (2), instead another hitherto unknown metastable cerium(III) acetate hydrate (4) was observed. It was only possible to determine a sum formula of Ce2(CH3COO)6(H2O)2 for 4.-
dc.description.sponsorshipFunding The authors thank the state of Schleswig-Holstein for the financial support. N.R., J.G., and N.S. acknowledge the support by the Deutsche Forschungsgemeinschaft (STO-643/15−1). J.T. acknowledges the support by the FWO and F.R.S.-FNRS (Belgium) under the Excellence of Science (EOS) program (‘PHOSPORE’– EOS reference number: 40,007,504). We acknowledge the European Synchrotron Radiation Facility (ESRF) for the provision of synchrotron radiation facilities under proposal number A26-2-999. Acknowledgments The authors thank the spectroscopic division of the department of inorganic chemistry at Kiel University for the conducted IR and EA measurements. The authors would like to thank Martin Rosenthal for assistance and support in using beamline BM26 at ESRF. Bastian Achenbach is acknowledged for contributing helpful ideas on this topic. Open Access funding enabled and organized by Projekt DEAL-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.rights2026 The Author(s). Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.-
dc.subject.othercerium-
dc.subject.othercoordination network-
dc.subject.otherin situ-
dc.subject.otherphase transformations-
dc.subject.othersolvothermal synthesis-
dc.titleSynthesis and Characterization of Anhydrous Cerium(III) Acetate, [Ce(CH3COO)3], and its Interconversions to Hydrated Phases-
dc.typeJournal Contribution-
local.format.pages7-
local.bibliographicCitation.jcatA1-
dc.description.notesStock, N (corresponding author), Univ Kiel, Inst Inorgan Chem, Kiel, Germany.; Stock, N (corresponding author), Univ Kiel, Kiel Nano Surface & Interface Sci KiNSIS, Kiel, Germany.-
dc.description.notesstock@ac.uni-kiel.de-
local.publisher.placePOSTFACH 101161, 69451 WEINHEIM, GERMANY-
local.type.refereedRefereed-
local.type.specifiedArticle-
local.bibliographicCitation.statusEarly view-
dc.identifier.doi10.1002/zaac.70148-
dc.identifier.isi001768675000001-
local.provider.typewosris-
local.description.affiliation[Ruser, Niklas; Behrens, Vanessa; Meier, Christoph; Steinke, Felix; Nather, Christian; Gosch, Jonas; Stock, Norbert] Univ Kiel, Inst Inorgan Chem, Kiel, Germany.-
local.description.affiliation[Theissen, Jennifer] Katholieke Univ Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect CMA, Leuven, Belgium.-
local.description.affiliation[Theissen, Jennifer] Hasselt Univ, Inst Mat Res imo imomec, Analyt & Circular Chem ACC, NMR Grp, Agoralaan, B-3590 Diepenbeek, Belgium.-
local.description.affiliation[Stock, Norbert] Univ Kiel, Kiel Nano Surface & Interface Sci KiNSIS, Kiel, Germany.-
local.uhasselt.internationalyes-
item.accessRightsOpen Access-
item.fulltextWith Fulltext-
item.contributorRuser, Niklas-
item.contributorBehrens, Vanessa-
item.contributorMeier, Christoph-
item.contributorTHEISSEN, Jennifer-
item.contributorSteinke, Felix-
item.contributorNather, Christian-
item.contributorGosch, Jonas-
item.contributorStock, Norbert-
item.fullcitationRuser, Niklas; Behrens, Vanessa; Meier, Christoph; THEISSEN, Jennifer; Steinke, Felix; Nather, Christian; Gosch, Jonas & Stock, Norbert (2026) Synthesis and Characterization of Anhydrous Cerium(III) Acetate, [Ce(CH3COO)3], and its Interconversions to Hydrated Phases. In: Zeitschrift Fur Anorganische Und Allgemeine Chemie,.-
crisitem.journal.issn0044-2313-
crisitem.journal.eissn1521-3749-
Appears in Collections:Research publications
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