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http://hdl.handle.net/1942/6096
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DC Field | Value | Language |
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dc.contributor.author | Bauschlicher, C.W. | - |
dc.contributor.author | MARTIN, Jan | - |
dc.contributor.author | Taylor, P.R. | - |
dc.date.accessioned | 2007-12-20T16:04:53Z | - |
dc.date.available | 2007-12-20T16:04:53Z | - |
dc.date.issued | 1999 | - |
dc.identifier.citation | Journal of physical chemistry: A, 103(38). p. 7715-7718 | - |
dc.identifier.issn | 1089-5639 | - |
dc.identifier.uri | http://hdl.handle.net/1942/6096 | - |
dc.description.abstract | The one-electron Douglas-Kroll approach, and perturbation theory including only the mass-velocity and Darwin terms, are used to compute the scalar relativistic contribution to the atomization energies of BS. Both approaches predict an approximately 0.7 kcal/mol reduction in the atomization energy. In combination with improved one-particle extrapolation techniques, this leads to a revised estimate for the heat of formation of gaseous boron, Delta H(f,0)degrees[B(g)] = 135.1 kcal/mol and Delta H(f,298)degrees[B(g)] = 136.3 kcal/mol, with error bars +/-0.75 kcal/mol or less. | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject.other | BASIS-SET LIMIT; WAVE-FUNCTIONS | - |
dc.title | The boron heat of formation revisited: relativistic effects on the BF3 atomization energy | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 7718 | - |
dc.identifier.issue | 38 | - |
dc.identifier.spage | 7715 | - |
dc.identifier.volume | 103 | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1021/jp991713a | - |
dc.identifier.isi | 000082782900023 | - |
item.fullcitation | Bauschlicher, C.W.; MARTIN, Jan & Taylor, P.R. (1999) The boron heat of formation revisited: relativistic effects on the BF3 atomization energy. In: Journal of physical chemistry: A, 103(38). p. 7715-7718. | - |
item.accessRights | Closed Access | - |
item.contributor | Bauschlicher, C.W. | - |
item.contributor | MARTIN, Jan | - |
item.contributor | Taylor, P.R. | - |
item.fulltext | No Fulltext | - |
Appears in Collections: | Research publications |
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