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http://hdl.handle.net/1942/9266
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DC Field | Value | Language |
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dc.contributor.author | Zhao, Jun | - |
dc.contributor.author | SWINNEN, Ann | - |
dc.contributor.author | Van Assche, Guy | - |
dc.contributor.author | MANCA, Jean | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.contributor.author | Van Mele, Bruno | - |
dc.date.accessioned | 2009-02-23T13:51:35Z | - |
dc.date.issued | 2009 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY B, 113(6). p. 1587-1591 | - |
dc.identifier.issn | 1520-6106 | - |
dc.identifier.uri | http://hdl.handle.net/1942/9266 | - |
dc.description.abstract | In this work, the phase diagram of poly(3-hexyl thiophene) (P3HT) and [6,6]-phenyl C-61-butyric acid methyl ester (PCBM) blends is measured by means of standard and modulated temperature differential scanning calorimetry. Blends were made by solvent-casting from chlorobenzene, as blends cast from toluene or 1,2-dichlorobenzene prove to retain effects of phase segregation during casting, hindering the determination of the phase diagram. The film morphology of P3HT/PCBM blends cast from chlorobenzene results from a dual crystallization behavior, in which the crystallization of each component is hindered by the other component. A single glass transition is observed for all compositions. The glass transition temperature (T-g) increases with increasing concentration of PCBM: from 12.1 degrees C for pure P3HT to 131.2 degrees C for pure PCBM. The observed T-g defines the operating window for the thermal annealing and explains the long-term instability of both the morphology and the photovoltaic performance of the P3HT/PCBM solar cells. | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Phase Diagram of P3HT/PCBM Blends and Its Implication for the Stability of Morphology | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 1591 | - |
dc.identifier.issue | 6 | - |
dc.identifier.spage | 1587 | - |
dc.identifier.volume | 113 | - |
local.format.pages | 5 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Zhao, Jun; Van Assche, Guy; Van Mele, Bruno] Vrije Univ Brussels, Fac Engn Sci, Dept Phys Chem & Polymer Sci, B-1050 Brussels, Belgium. [Swinnen, Ann; Manca, Jean; Vanderzande, Dirk] Hasselt Univ, Inst Mat Res, B-3590 Diepenbeek, Belgium. [Manca, Jean; Vanderzande, Dirk] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium. | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1021/jp804151a | - |
dc.identifier.isi | 000263134500006 | - |
item.contributor | Zhao, Jun | - |
item.contributor | SWINNEN, Ann | - |
item.contributor | Van Assche, Guy | - |
item.contributor | MANCA, Jean | - |
item.contributor | VANDERZANDE, Dirk | - |
item.contributor | Van Mele, Bruno | - |
item.validation | ecoom 2010 | - |
item.fulltext | No Fulltext | - |
item.accessRights | Closed Access | - |
item.fullcitation | Zhao, Jun; SWINNEN, Ann; Van Assche, Guy; MANCA, Jean; VANDERZANDE, Dirk & Van Mele, Bruno (2009) Phase Diagram of P3HT/PCBM Blends and Its Implication for the Stability of Morphology. In: JOURNAL OF PHYSICAL CHEMISTRY B, 113(6). p. 1587-1591. | - |
crisitem.journal.issn | 1520-6106 | - |
crisitem.journal.eissn | 1520-5207 | - |
Appears in Collections: | Research publications |
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