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http://hdl.handle.net/1942/9270
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DC Field | Value | Language |
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dc.contributor.author | Angulo, Gonzalo | - |
dc.contributor.author | Kapturkiewicz, Andrzej | - |
dc.contributor.author | PALMAERTS, Arne | - |
dc.contributor.author | LUTSEN, Laurence | - |
dc.contributor.author | CLEIJ, Thomas | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.date.accessioned | 2009-02-24T10:23:50Z | - |
dc.date.issued | 2009 | - |
dc.identifier.citation | ELECTROCHIMICA ACTA, 54(5). p. 1584-1588 | - |
dc.identifier.issn | 0013-4686 | - |
dc.identifier.uri | http://hdl.handle.net/1942/9270 | - |
dc.description.abstract | Poly(p-fluoranthenevinylenes) and their dithiocarbamate precursors have been deposited on indium-tin oxide electrodes and electrochemical properties of the obtained films have been investigated by means of cyclic voltammetry studies in acetonitrile solutions containing 0.1 M (n-C4H9)(4)NBF4 as supporting electrolyte. It has been found that: all investigated polymers display well pronounced n-doping processes. Electrochemical reduction of the dithiocarbamate precursors seems robe associated with C-S bond cleavage with elimination of -SC(S)N(C2H5)(2) group. In view of UV-vis spectroscopic data the obtained products, tentatively identified as polymers containing fluoranthene units connected by -CH2-CH2- bridges, are somewhat less conjugated than the corresponding poly(p-fluoranthenevinylenes). Reversible electrochemical reduction of poly(p-fluoranthenethanes) occurs at potentials only somewhat (ca. 0.1 V) more negative as found for their poly(p-fluoranthenevinylenes) analogues suggesting relatively weak coupling between fluoranthene kernels in both kinds of investigated polymers. (c) 2008 Elsevier Ltd. All rights reserved. | - |
dc.language.iso | en | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject.other | n-Type polymers; Polyfluoranthenes; Thin film electrochemistry; Cyclic voltammetry | - |
dc.title | Cyclic voltammetry studies of n-type polymers with non-alternant fluoranthene units | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 1588 | - |
dc.identifier.issue | 5 | - |
dc.identifier.spage | 1584 | - |
dc.identifier.volume | 54 | - |
local.format.pages | 5 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Angulo, Gonzalo; Kapturkiewicz, Andrzej] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland. [Palmaerts, Arne; Cleij, Thomas J.; Vanderzande, Dirk] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Lutsen, Laurence; Vanderzande, Dirk] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium. | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1016/j.electacta.2008.09.045 | - |
dc.identifier.isi | 000263006100027 | - |
item.fulltext | No Fulltext | - |
item.contributor | Angulo, Gonzalo | - |
item.contributor | Kapturkiewicz, Andrzej | - |
item.contributor | PALMAERTS, Arne | - |
item.contributor | LUTSEN, Laurence | - |
item.contributor | CLEIJ, Thomas | - |
item.contributor | VANDERZANDE, Dirk | - |
item.fullcitation | Angulo, Gonzalo; Kapturkiewicz, Andrzej; PALMAERTS, Arne; LUTSEN, Laurence; CLEIJ, Thomas & VANDERZANDE, Dirk (2009) Cyclic voltammetry studies of n-type polymers with non-alternant fluoranthene units. In: ELECTROCHIMICA ACTA, 54(5). p. 1584-1588. | - |
item.accessRights | Closed Access | - |
item.validation | ecoom 2010 | - |
crisitem.journal.issn | 0013-4686 | - |
crisitem.journal.eissn | 1873-3859 | - |
Appears in Collections: | Research publications |
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