Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/9270
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dc.contributor.authorAngulo, Gonzalo-
dc.contributor.authorKapturkiewicz, Andrzej-
dc.contributor.authorPALMAERTS, Arne-
dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorCLEIJ, Thomas-
dc.contributor.authorVANDERZANDE, Dirk-
dc.date.accessioned2009-02-24T10:23:50Z-
dc.date.issued2009-
dc.identifier.citationELECTROCHIMICA ACTA, 54(5). p. 1584-1588-
dc.identifier.issn0013-4686-
dc.identifier.urihttp://hdl.handle.net/1942/9270-
dc.description.abstractPoly(p-fluoranthenevinylenes) and their dithiocarbamate precursors have been deposited on indium-tin oxide electrodes and electrochemical properties of the obtained films have been investigated by means of cyclic voltammetry studies in acetonitrile solutions containing 0.1 M (n-C4H9)(4)NBF4 as supporting electrolyte. It has been found that: all investigated polymers display well pronounced n-doping processes. Electrochemical reduction of the dithiocarbamate precursors seems robe associated with C-S bond cleavage with elimination of -SC(S)N(C2H5)(2) group. In view of UV-vis spectroscopic data the obtained products, tentatively identified as polymers containing fluoranthene units connected by -CH2-CH2- bridges, are somewhat less conjugated than the corresponding poly(p-fluoranthenevinylenes). Reversible electrochemical reduction of poly(p-fluoranthenethanes) occurs at potentials only somewhat (ca. 0.1 V) more negative as found for their poly(p-fluoranthenevinylenes) analogues suggesting relatively weak coupling between fluoranthene kernels in both kinds of investigated polymers. (c) 2008 Elsevier Ltd. All rights reserved.-
dc.language.isoen-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subject.othern-Type polymers; Polyfluoranthenes; Thin film electrochemistry; Cyclic voltammetry-
dc.titleCyclic voltammetry studies of n-type polymers with non-alternant fluoranthene units-
dc.typeJournal Contribution-
dc.identifier.epage1588-
dc.identifier.issue5-
dc.identifier.spage1584-
dc.identifier.volume54-
local.format.pages5-
local.bibliographicCitation.jcatA1-
dc.description.notes[Angulo, Gonzalo; Kapturkiewicz, Andrzej] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland. [Palmaerts, Arne; Cleij, Thomas J.; Vanderzande, Dirk] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Lutsen, Laurence; Vanderzande, Dirk] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium.-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1016/j.electacta.2008.09.045-
dc.identifier.isi000263006100027-
item.fulltextNo Fulltext-
item.accessRightsClosed Access-
item.contributorLUTSEN, Laurence-
item.contributorVANDERZANDE, Dirk-
item.contributorCLEIJ, Thomas-
item.contributorAngulo, Gonzalo-
item.contributorPALMAERTS, Arne-
item.contributorKapturkiewicz, Andrzej-
item.fullcitationAngulo, Gonzalo; Kapturkiewicz, Andrzej; PALMAERTS, Arne; LUTSEN, Laurence; CLEIJ, Thomas & VANDERZANDE, Dirk (2009) Cyclic voltammetry studies of n-type polymers with non-alternant fluoranthene units. In: ELECTROCHIMICA ACTA, 54(5). p. 1584-1588.-
item.validationecoom 2010-
crisitem.journal.issn0013-4686-
crisitem.journal.eissn1873-3859-
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