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|Title:||Chemical Interactions at Metal/Molecule Interfaces in Molecular Junctions-A Pathway Towards Molecular Recognition||Authors:||Manolova, Milo
Kolb, Dieter M.
|Issue Date:||2009||Publisher:||WILEY-V C H VERLAG GMBH||Source:||ADVANCED MATERIALS, 21(3). p. 320-324||Abstract:||A 4-aminothiophenol self-assembled monolayer (see image) is prepared on top of a Au(111) crystal, which is subsequently metallized by a nearly closed Pd overlayer of monoatomic height. Analysis of its structural setup and electronic properties reveals that the monolayer consists of a minimum of two molecular layers, and strong chemical interactions between the metal overlayer and the amino groups are found to play a decisive role in determining the overall electronic, and thus the transport properties, of the layer/metal contact.||Notes:||[Boyen, Hans-Gerd] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Manolova, Milo; Ivanova, Valentina; Kolb, Dieter M.] Univ Ulm, Inst Electrochem, D-89069 Ulm, Germany. [Kucera, Jan; Gross, Axel] Univ Ulm, Inst Theoret Chem, D-89069 Ulm, Germany. [Romanyuk, Andriy; Oelhafen, Peter] Univ Basel, Inst Phys, CH-4056 Basel, Switzerland.||Document URI:||http://hdl.handle.net/1942/9274||ISSN:||0935-9648||e-ISSN:||1521-4095||DOI:||10.1002/adma.200901634||ISI #:||000263081700007||Category:||A1||Type:||Journal Contribution||Validations:||ecoom 2010|
|Appears in Collections:||Research publications|
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