The infrared optical absorption spectra of the functionalized nanocrystalline diamond surface

Abstract

We propose a new method of detecting the functional groups at the NCD surface based on the interfrence-free infrared reflection absorption spectroscopy of p-polarized IR light at Brewster's angle of incidence (BA-IRRAS). We report IR absorbance spectra of a linker molecule monolayer (10-undecenoic acid) covalently bonded to the NCD surface with and without DNA fragments coupled to it, and IR spectra of organosilane polymer coatings deposited on NCD surface by the spin coating technology. The homogeneity of the surface coatings was monitored by fluorescence microscopy. (C) 2008 Elsevier B.V. All rights reserved.