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http://hdl.handle.net/1942/9998
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DC Field | Value | Language |
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dc.contributor.author | PALMAERTS, Arne | - |
dc.contributor.author | LUTSEN, Laurence | - |
dc.contributor.author | CLEIJ, Thomas | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.contributor.author | Pivrikas, Almantas | - |
dc.contributor.author | Neugebauer, Helmut | - |
dc.contributor.author | Sariciftci, Niyazi Serdar | - |
dc.date.accessioned | 2009-11-20T15:09:47Z | - |
dc.date.available | 2009-11-20T15:09:47Z | - |
dc.date.issued | 2009 | - |
dc.identifier.citation | POLYMER, 50(21). p. 5007-5015 | - |
dc.identifier.issn | 0032-3861 | - |
dc.identifier.uri | http://hdl.handle.net/1942/9998 | - |
dc.description.abstract | Considerable interest exists in the development of novel n-type conjugated polymers, since many currently available polymer systems have insufficient electron mobility and/or electron affinity. In this work, a universal synthesis route is presented towards a new class of n-type conjugated polymers, i.e. poly(p-fluoranthene vinylene) (PFV) and its derivatives. This route is illustrated with three examples, i.e. unsubstituted PFV and functionalized hexyl-PFV and dodecyl-PFV. All polymers have been synthesized via the dithiocarbamate precursor route. Solubility was introduced by incorporation of alkyl side chains, which leads to a significantly enhanced purity and processability as compared to unsubstituted PFV. Under the applied electrochemical conditions PFV-type polymers demonstrate typical n-type behavior. Additional CELIV mobility measurements on dodecyl-PFV reveal an excellent electron mobility, mu(e) = 1.4 x 10(-4) cm(2)/Vs. Hence, poly(p-fluoranthene vinylene) and its derivatives are promising n-type materials for organic optoelectronic applications. (C) 2009 Elsevier Ltd. All rights reserved. | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCI LTD | - |
dc.subject.other | Conjugated polymers; Organic electronics; PPV-type polymers | - |
dc.title | Development of novel processable electron accepting conjugated polymers containing fluoranthene units in the main chain | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 5015 | - |
dc.identifier.issue | 21 | - |
dc.identifier.spage | 5007 | - |
dc.identifier.volume | 50 | - |
local.format.pages | 9 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Palmaerts, Arne; Cleij, Thomas J.; Vanderzande, Dirk] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Lutsen, Laurence; Vanderzande, Dirk] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium. [Pivrikas, Almantas; Neugebauer, Helmut; Sariciftci, Niyazi Serdar] Johannes Kepler Univ Linz, Dept Phys Chem, A-4040 Linz, Austria. [Pivrikas, Almantas; Neugebauer, Helmut; Sariciftci, Niyazi Serdar] Linz Inst Organ Solar Cells LIOS, A-4040 Linz, Austria. | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1016/j.polymer.2009.08.031 | - |
dc.identifier.isi | 000270705700004 | - |
item.fulltext | No Fulltext | - |
item.contributor | PALMAERTS, Arne | - |
item.contributor | LUTSEN, Laurence | - |
item.contributor | CLEIJ, Thomas | - |
item.contributor | VANDERZANDE, Dirk | - |
item.contributor | Pivrikas, Almantas | - |
item.contributor | Neugebauer, Helmut | - |
item.contributor | Sariciftci, Niyazi Serdar | - |
item.accessRights | Closed Access | - |
item.fullcitation | PALMAERTS, Arne; LUTSEN, Laurence; CLEIJ, Thomas; VANDERZANDE, Dirk; Pivrikas, Almantas; Neugebauer, Helmut & Sariciftci, Niyazi Serdar (2009) Development of novel processable electron accepting conjugated polymers containing fluoranthene units in the main chain. In: POLYMER, 50(21). p. 5007-5015. | - |
item.validation | ecoom 2010 | - |
crisitem.journal.issn | 0032-3861 | - |
crisitem.journal.eissn | 1873-2291 | - |
Appears in Collections: | Research publications |
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