Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/9998
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dc.contributor.authorPALMAERTS, Arne-
dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorCLEIJ, Thomas-
dc.contributor.authorVANDERZANDE, Dirk-
dc.contributor.authorPivrikas, Almantas-
dc.contributor.authorNeugebauer, Helmut-
dc.contributor.authorSariciftci, Niyazi Serdar-
dc.date.accessioned2009-11-20T15:09:47Z-
dc.date.available2009-11-20T15:09:47Z-
dc.date.issued2009-
dc.identifier.citationPOLYMER, 50(21). p. 5007-5015-
dc.identifier.issn0032-3861-
dc.identifier.urihttp://hdl.handle.net/1942/9998-
dc.description.abstractConsiderable interest exists in the development of novel n-type conjugated polymers, since many currently available polymer systems have insufficient electron mobility and/or electron affinity. In this work, a universal synthesis route is presented towards a new class of n-type conjugated polymers, i.e. poly(p-fluoranthene vinylene) (PFV) and its derivatives. This route is illustrated with three examples, i.e. unsubstituted PFV and functionalized hexyl-PFV and dodecyl-PFV. All polymers have been synthesized via the dithiocarbamate precursor route. Solubility was introduced by incorporation of alkyl side chains, which leads to a significantly enhanced purity and processability as compared to unsubstituted PFV. Under the applied electrochemical conditions PFV-type polymers demonstrate typical n-type behavior. Additional CELIV mobility measurements on dodecyl-PFV reveal an excellent electron mobility, mu(e) = 1.4 x 10(-4) cm(2)/Vs. Hence, poly(p-fluoranthene vinylene) and its derivatives are promising n-type materials for organic optoelectronic applications. (C) 2009 Elsevier Ltd. All rights reserved.-
dc.language.isoen-
dc.publisherELSEVIER SCI LTD-
dc.subject.otherConjugated polymers; Organic electronics; PPV-type polymers-
dc.titleDevelopment of novel processable electron accepting conjugated polymers containing fluoranthene units in the main chain-
dc.typeJournal Contribution-
dc.identifier.epage5015-
dc.identifier.issue21-
dc.identifier.spage5007-
dc.identifier.volume50-
local.format.pages9-
local.bibliographicCitation.jcatA1-
dc.description.notes[Palmaerts, Arne; Cleij, Thomas J.; Vanderzande, Dirk] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Lutsen, Laurence; Vanderzande, Dirk] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium. [Pivrikas, Almantas; Neugebauer, Helmut; Sariciftci, Niyazi Serdar] Johannes Kepler Univ Linz, Dept Phys Chem, A-4040 Linz, Austria. [Pivrikas, Almantas; Neugebauer, Helmut; Sariciftci, Niyazi Serdar] Linz Inst Organ Solar Cells LIOS, A-4040 Linz, Austria.-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1016/j.polymer.2009.08.031-
dc.identifier.isi000270705700004-
item.fullcitationPALMAERTS, Arne; LUTSEN, Laurence; CLEIJ, Thomas; VANDERZANDE, Dirk; Pivrikas, Almantas; Neugebauer, Helmut & Sariciftci, Niyazi Serdar (2009) Development of novel processable electron accepting conjugated polymers containing fluoranthene units in the main chain. In: POLYMER, 50(21). p. 5007-5015.-
item.fulltextNo Fulltext-
item.accessRightsClosed Access-
item.validationecoom 2010-
item.contributorLUTSEN, Laurence-
item.contributorVANDERZANDE, Dirk-
item.contributorCLEIJ, Thomas-
item.contributorNeugebauer, Helmut-
item.contributorPALMAERTS, Arne-
item.contributorPivrikas, Almantas-
item.contributorSariciftci, Niyazi Serdar-
crisitem.journal.issn0032-3861-
crisitem.journal.eissn1873-2291-
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