Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/14591
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dc.contributor.authorDommanget, Cedric-
dc.contributor.authorBoisson, Christophe-
dc.contributor.authorCharleux, Bernadette-
dc.contributor.authorD'Agosto, Franck-
dc.contributor.authorMonteil, Vincent-
dc.contributor.authorBoisson, Fernande-
dc.contributor.authorJUNKERS, Tanja-
dc.contributor.authorBarner-Kowollik, Christopher-
dc.contributor.authorGuillaneuf, Yohann-
dc.contributor.authorGigmes, Didier-
dc.date.accessioned2013-02-21T08:24:34Z-
dc.date.available2013-02-21T08:24:34Z-
dc.date.issued2013-
dc.identifier.citationMACROMOLECULES, 46 (1), p. 29-36-
dc.identifier.issn0024-9297-
dc.identifier.urihttp://hdl.handle.net/1942/14591-
dc.description.abstractEnhanced spin capturing polymerization (ESCP)-a recent and versatile technique in the field of controlled radical polymerization-achieves control over molecular weights and the synthesis of complex copolymer structures for a wide range of monomers. In the present work, the use of ESCP was extended to the radical polymerization of ethylene under mild conditions (low temperature and medium ethylene pressure) using a nitrone as spin trapping agent. It was demonstrated that the evolution of polyethylene (PE) molecular weight can be accurately described by classical ESCP kinetic equations. A PE bearing a midchain alkoxyamine function was thus obtained with high selectivity (90%). A more complex structure was produced from the radical polymerization of ethylene in the presence of a midchain alkoxyamine-functionalized polystyrene (PS) synthesized by ESCP in the form of ABA triblock copolymer (where A is polystyrene and B polyethylene).-
dc.description.sponsorshipT.J. is grateful for funding from the Fonds Wetenschappelijk Onderzoek (FWO) via project G.0491.11N and the Odysseus-scheme. C.B.-K. acknowledges continued support from the Karlsruhe Institute of Technology (KIT) in the context of the Excellence Initiative for leading German universities as well as the German Research Council (DFG). C.D. thanks the "Ministere de la Recherche et de l'Enseignement Superieur" for fellowship. V.M. acknowledges ANR and competitiveness clusters AXELERA and PLASTIPOLIS for financial support (project FRaPE; ANR 2011 JS08 008 01).-
dc.language.isoen-
dc.publisherAMER CHEMICAL SOC-
dc.subject.otherPolymer Science-
dc.titleEnhanced Spin Capturing Polymerization of Ethylene-
dc.typeJournal Contribution-
dc.identifier.epage36-
dc.identifier.issue1-
dc.identifier.spage29-
dc.identifier.volume46-
local.format.pages8-
local.bibliographicCitation.jcatA1-
dc.description.notes[Dommanget, Cedric; Boisson, Christophe; Charleux, Bernadette; D'Agosto, Franck; Monteil, Vincent] Univ Lyon 1, Lab Chim Catalyse Polymeres & Proc C2P2, LCPP Team, CPE Lyon,CNRS,UMR 5265, F-69616 Villeurbanne, France. [Boisson, Fernande] Univ Lyon, Serv RMN Polymeres ICL, CNRS, UMR 5223,INSA Lyon, F-69621 Villeurbanne, France. [Junkers, Thomas] Univ Hasselt, Inst Mat Res, Polymer React Design Grp, B-3590 Diepenbeek, Belgium. [Barner-Kowollik, Christopher] Karlsruhe Inst Technol, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany. [Guillaneuf, Yohann; Gigmes, Didier] Aix Marseille Univ, CNRS, Inst Chim Radicalaire, UMR 7273, F-13397 Marseille 20, France. monteil@lcpp.cpe.fr; thomas.junkers@uhasselt.be; christopher.barner-kowollik@kit.edu; didier.gigmes@univ-amu.fr-
local.publisher.placeWASHINGTON-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1021/ma3014806-
dc.identifier.isi000313303600005-
item.fulltextWith Fulltext-
item.accessRightsRestricted Access-
item.contributorBoisson, Christophe-
item.contributorGigmes, Didier-
item.contributorGuillaneuf, Yohann-
item.contributorD'Agosto, Franck-
item.contributorDommanget, Cedric-
item.contributorJUNKERS, Tanja-
item.contributorBarner-Kowollik, Christopher-
item.contributorBoisson, Fernande-
item.contributorCharleux, Bernadette-
item.contributorMonteil, Vincent-
item.fullcitationDommanget, Cedric; Boisson, Christophe; Charleux, Bernadette; D'Agosto, Franck; Monteil, Vincent; Boisson, Fernande; JUNKERS, Tanja; Barner-Kowollik, Christopher; Guillaneuf, Yohann & Gigmes, Didier (2013) Enhanced Spin Capturing Polymerization of Ethylene. In: MACROMOLECULES, 46 (1), p. 29-36.-
item.validationecoom 2014-
crisitem.journal.issn0024-9297-
crisitem.journal.eissn1520-5835-
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