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Title: | Enhanced Spin Capturing Polymerization of Ethylene | Authors: | Dommanget, Cedric Boisson, Christophe Charleux, Bernadette D'Agosto, Franck Monteil, Vincent Boisson, Fernande JUNKERS, Tanja Barner-Kowollik, Christopher Guillaneuf, Yohann Gigmes, Didier |
Issue Date: | 2013 | Publisher: | AMER CHEMICAL SOC | Source: | MACROMOLECULES, 46 (1), p. 29-36 | Abstract: | Enhanced spin capturing polymerization (ESCP)-a recent and versatile technique in the field of controlled radical polymerization-achieves control over molecular weights and the synthesis of complex copolymer structures for a wide range of monomers. In the present work, the use of ESCP was extended to the radical polymerization of ethylene under mild conditions (low temperature and medium ethylene pressure) using a nitrone as spin trapping agent. It was demonstrated that the evolution of polyethylene (PE) molecular weight can be accurately described by classical ESCP kinetic equations. A PE bearing a midchain alkoxyamine function was thus obtained with high selectivity (90%). A more complex structure was produced from the radical polymerization of ethylene in the presence of a midchain alkoxyamine-functionalized polystyrene (PS) synthesized by ESCP in the form of ABA triblock copolymer (where A is polystyrene and B polyethylene). | Notes: | [Dommanget, Cedric; Boisson, Christophe; Charleux, Bernadette; D'Agosto, Franck; Monteil, Vincent] Univ Lyon 1, Lab Chim Catalyse Polymeres & Proc C2P2, LCPP Team, CPE Lyon,CNRS,UMR 5265, F-69616 Villeurbanne, France. [Boisson, Fernande] Univ Lyon, Serv RMN Polymeres ICL, CNRS, UMR 5223,INSA Lyon, F-69621 Villeurbanne, France. [Junkers, Thomas] Univ Hasselt, Inst Mat Res, Polymer React Design Grp, B-3590 Diepenbeek, Belgium. [Barner-Kowollik, Christopher] Karlsruhe Inst Technol, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany. [Guillaneuf, Yohann; Gigmes, Didier] Aix Marseille Univ, CNRS, Inst Chim Radicalaire, UMR 7273, F-13397 Marseille 20, France. monteil@lcpp.cpe.fr; thomas.junkers@uhasselt.be; christopher.barner-kowollik@kit.edu; didier.gigmes@univ-amu.fr | Keywords: | Polymer Science | Document URI: | http://hdl.handle.net/1942/14591 | ISSN: | 0024-9297 | e-ISSN: | 1520-5835 | DOI: | 10.1021/ma3014806 | ISI #: | 000313303600005 | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2014 |
Appears in Collections: | Research publications |
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