Identifiability via the Method of Similarity Transformation of Models for Reversible Intermolecular Two-State Excited-State Processes with Species-Dependent Rotational Diffusion or with Added Quencher

Abstract

Deterministic identifiability analyses via similarity transformation are presented for two kinetic models of a reversible intermolecular two-state excited-state process in isotropic environments: (a) with coupled species-dependent rotational diffusion described by Brownian reorientation, and (b) with added quencher. For (a), both spherically and cylindrically symmetric rotors, with no change in the principal axes of rotation in the latter, are considered. The fluorescence ...