Please use this identifier to cite or link to this item:
http://hdl.handle.net/1942/17758
Title: | Electronic Structure of the Positive Radical of C-13-Labeled Poly(3-Octylthienylene Vinylene) Polymer | Authors: | Ling, Yun DILIEN, Hanne VANDERZANDE, Dirk ADRIAENSENS, Peter VAN DOORSLAER, Sabine |
Issue Date: | 2014 | Publisher: | SPRINGER WIEN | Source: | APPLIED MAGNETIC RESONANCE, 45 (9), p. 827-839 | Abstract: | Poly(3-octylthienylene vinylene) (O-PTV) has a great potential as low-bandgap p-type semiconductor for photovoltaic applications. Here, the positive radical state (positive polaron) is induced chemically in the O-PTV polymer in which the vinylene sites are selectively C-13-labeled. Using multi-frequency continuous wave and pulsed electron paramagnetic resonance, the g tensor and maximum H-1 and C-13 hyperfine couplings are determined. A comparative density functional theory (DFT) analysis of PTV-like oligomers is performed. The experimental parameters suggest a larger localization of the positive polaron than follows from the DFT analysis. The counter anion may play a crucial role in localizing the polaron. | Notes: | [Ling, Yun; Van Doorslaer, Sabine] Univ Antwerp, BIMEF Lab, Dept Phys, B-2610 Antwerp, Belgium. [Dilien, Hanne; Vanderzande, Dirk; Adriaensens, Peter J.] Hasselt Univ, Inst Mat Res IMO IMOMEC, B-3590 Diepenbeek, Belgium. [Vanderzande, Dirk; Adriaensens, Peter J.] IMEC, IMOMEC Assoc Lab, B-3590 Diepenbeek, Belgium. | Document URI: | http://hdl.handle.net/1942/17758 | ISSN: | 0937-9347 | e-ISSN: | 1613-7507 | DOI: | 10.1007/s00723-014-0561-3 | ISI #: | 000342413100004 | Rights: | © Springer-Verlag Wien 2014 | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2015 |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
art%3A10.1007%2Fs00723-014-0561-3.pdf Restricted Access | 589.11 kB | Adobe PDF | View/Open Request a copy |
SCOPUSTM
Citations
2
checked on Sep 5, 2020
WEB OF SCIENCETM
Citations
2
checked on Aug 3, 2024
Page view(s)
182
checked on Apr 26, 2023
Download(s)
146
checked on Apr 26, 2023
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.