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http://hdl.handle.net/1942/18718
Title: | Watching polymers grow: real time monitoring of polymerizations via an on-line ESI-MS/microreactor coupling | Authors: | HAVEN, Joris VANDENBERGH, Joke JUNKERS, Tanja |
Issue Date: | 2015 | Publisher: | ROYAL SOC CHEMISTRY | Source: | CHEMICAL COMMUNICATIONS, 51 (22), p. 4611-4614 | Abstract: | A technique for the continuous on-line monitoring of polymerization processes by electrospray ionization mass spectrometry (ESI-MS) is presented via coupling with a commercial microreactor system. The potential is demonstrated by monitoring polymerizations in real time under synthesis conditions. Furthermore, a single acrylate monomer insertion into a oligo-RAFT agent, as used in the synthesis of mono-disperse sequence controlled materials, was optimized by on-line screening of reaction conditions. | Notes: | [Haven, Joris J.; Vandenbergh, Joke; Junkers, Thomas] Univ Hasselt, Polymer React Design Grp, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. thomas.junkers@uhasselt.be | Document URI: | http://hdl.handle.net/1942/18718 | ISSN: | 1359-7345 | e-ISSN: | 1364-548X | DOI: | 10.1039/c4cc10426a | ISI #: | 000350486300015 | Rights: | This journal is © The Royal Society of Chemistry 2015. | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2016 |
Appears in Collections: | Research publications |
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File | Description | Size | Format | |
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haven 1.pdf Restricted Access | Published version | 1.62 MB | Adobe PDF | View/Open Request a copy |
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