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http://hdl.handle.net/1942/19164| Title: | Continuous poly(2-oxazoline) triblock copolymer synthesis in a microfluidic reactor cascade | Authors: | BAETEN, Evelien Verbraeken, Bart Hoogenboom, Richard JUNKERS, Tanja |
Issue Date: | 2015 | Publisher: | ROYAL SOC CHEMISTRY | Source: | CHEMICAL COMMUNICATIONS, 51 (58), p. 11701-11704 | Abstract: | Cationic ring-opening polymerizations of 2-oxazolines were investigated in continuous microflow reactors. Fast homopolymerizations of 2-ethyl-2-oxazoline (EtOx) and 2-n-propyl-2-oxazoline (nPropOx) were carried out up to 180 degrees C, yielding well-controlled polymers. Also well-defined diblock and triblock copolymers were produced in a microfluidic reactor cascade, demonstrating the high value of microflow synthesis for the built-up of advanced poly(2-oxazoline)-based polymers. | Notes: | [Baeten, Evelien; Junkers, Thomas] Univ Hasselt, Polymer React Design Grp, Inst Mat Res IMO, B-3500 Hasselt, Belgium. [Verbraeken, Bart; Hoogenboom, Richard] Univ Ghent, Supramol Chem Grp, Dept Organ & Macromol Chem, B-9000 Ghent, Belgium. [Junkers, Thomas] IMEC Associated Lab IMOMEC, B-3590 Diepenbeek, Belgium. | Document URI: | http://hdl.handle.net/1942/19164 | ISSN: | 1359-7345 | e-ISSN: | 1364-548X | DOI: | 10.1039/c5cc04319k | ISI #: | 000357618200039 | Rights: | This journal is © The Royal Society of Chemistry 2015 | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2016 |
| Appears in Collections: | Research publications |
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|---|---|---|---|---|
| c5cc04319k.pdf Restricted Access | 1.72 MB | Adobe PDF | View/Open Request a copy |
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