Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media

Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/19840

Title:	Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media
Authors:	Marrocchi, Assunta ADRIAENSENS, Peter Bartollini, Elena Barkakaty, Balaka CARLEER, Robert Chen, Jihua Hensley, Dale K. TASSI, Marco Vaccaro, Luigi Petrucci, Chiara
Issue Date:	2015
Source:	EUROPEAN POLYMER JOURNAL, 73, p. 391-401
Abstract:	A novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1,4-bis (4-vinylphenoxy)benzene cross-linker, is introduced; SP-immobilized 1,5,7-triazabicyclo [4.4.0]dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.
Notes:	Marrocchi, A (reprint author), Univ Perugia, CEMIN Dipartimento Chim Biol & Biotecnol, Lab Green Synthet Organ Chem, Via Elce Sotto 8, I-06123 Perugia, Italy. assunta.marrocchi@unipg.it; luigi.vaccaro@unipg.it
Keywords:	polystyrenes; gel-type resins; polymer supports; heterogeneous catalyst; green chemistry
Document URI:	http://hdl.handle.net/1942/19840
ISSN:	0014-3057
e-ISSN:	1873-1945
DOI:	10.1016/j.eurpolymj.2015.10.002
ISI #:	000366536900034
Rights:	© 2015 Published by Elsevier Ltd.
Category:	A1
Type:	Journal Contribution
Validations:	ecoom 2017
Appears in Collections:	Research publications

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