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http://hdl.handle.net/1942/19840
Title: | Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media | Authors: | Marrocchi, Assunta ADRIAENSENS, Peter Bartollini, Elena Barkakaty, Balaka CARLEER, Robert Chen, Jihua Hensley, Dale K. TASSI, Marco Vaccaro, Luigi Petrucci, Chiara |
Issue Date: | 2015 | Source: | EUROPEAN POLYMER JOURNAL, 73, p. 391-401 | Abstract: | A novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1,4-bis (4-vinylphenoxy)benzene cross-linker, is introduced; SP-immobilized 1,5,7-triazabicyclo [4.4.0]dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated. | Notes: | Marrocchi, A (reprint author), Univ Perugia, CEMIN Dipartimento Chim Biol & Biotecnol, Lab Green Synthet Organ Chem, Via Elce Sotto 8, I-06123 Perugia, Italy. assunta.marrocchi@unipg.it; luigi.vaccaro@unipg.it | Keywords: | polystyrenes; gel-type resins; polymer supports; heterogeneous catalyst; green chemistry | Document URI: | http://hdl.handle.net/1942/19840 | ISSN: | 0014-3057 | e-ISSN: | 1873-1945 | DOI: | 10.1016/j.eurpolymj.2015.10.002 | ISI #: | 000366536900034 | Rights: | © 2015 Published by Elsevier Ltd. | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2017 |
Appears in Collections: | Research publications |
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1-s2.0-S0014305715300069-main.pdf Restricted Access | Published version | 1.77 MB | Adobe PDF | View/Open Request a copy |
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