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http://hdl.handle.net/1942/27167
Title: | Sequence-definition from controlled polymerization: the next generation of materials | Authors: | DE NEVE, Jeroen HAVEN, Joris MAES, Lowie JUNKERS, Tanja |
Issue Date: | 2018 | Source: | Polymer Chemistry, 9 (38), p. 4692-4705 | Abstract: | An overview is given on the state-of-the-art in synthesis of sequence-controlled and sequence-defined oligomers and polymers. These materials constitute chains in which chemical information is encoded along the backbone either as multiblock copolymers (controlled) or as monodisperse sequences of single monomers (defined). Focus is placed on reversible-deactivation radical polymerization techniques as these give access to a broad variety of chemical functionalities and allow for simple and fast synthesis procedures. Sequence-controlled and -defined materials have the ability to re-shape materials chemistry due to their close resemblance to biopolymers regarding structural uniformity. The field is at the edge of being able to start exploring the distinct properties that such synthetic macromolecules may have. | Notes: | Junkers, T (reprint author), Monash Univ, Sch Chem, Polymer React Design Grp, 19 Rainforest Walk, Clayton, Vic 3800, Australia. tanja.junkers@monash.edu | Document URI: | http://hdl.handle.net/1942/27167 | ISSN: | 1759-9954 | e-ISSN: | 1759-9962 | DOI: | 10.1039/C8PY01190G | ISI #: | 000448346300001 | Rights: | The authors are grateful for funding from Hasselt University and Monash University | Category: | A1 | Type: | Journal Contribution |
Appears in Collections: | Research publications |
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Sequence-definition from controlled polymerization the next generation of materials_De Neve_2018.pdf Restricted Access | Published version | 2.41 MB | Adobe PDF | View/Open Request a copy |
Author version_Sequence-definition from controlled polymerization the next generation of materials_De Neve_2018.pdf | Peer-reviewed author version | 1.5 MB | Adobe PDF | View/Open |
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