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|Title:||Mechanistic study on the Gilch and the Sulfinyl polymerisation routes||Authors:||HONTIS, Lieve
|Issue Date:||2001||Publisher:||ELSEVIER SCIENCE SA||Source:||SYNTHETIC METALS, 119(1-3). p. 135-136||Abstract:||Poly-(p-phenylene vinylene) (PPV) and its derivatives remain the most used class of conjugated polymers for use as active layer in P-LEDs. To obtain the desired polymer several synthetic methods have been developed; most of them based on similar chemistry. However, the nature of the underlying mechanism of these type of p-quinodimethane based polymerisations is still unclear; both anionic and radical mechanisms have been proposed. Recently, we investigated the influence of several additives on the Gilch and the Sulfinyl polymerisation towards OC1C10-PPV in THF in an attempt to bring some clarification on the matter.||Notes:||Limburgs Univ Ctr, Lab Organ & Polymer Chem, Mat Res Inst, Div Chem, B-3590 Diepenbeek, Belgium.Vanderzande, D, Limburgs Univ Ctr, Lab Organ & Polymer Chem, Mat Res Inst, Div Chem, Univ Campus, B-3590 Diepenbeek, Belgium.||Keywords:||polymerisation mechanism; P-LEDs; poly(phenylene vinylene) and derivatives; Gilch and Sulfinyl route||Document URI:||http://hdl.handle.net/1942/2756||ISSN:||0379-6779||e-ISSN:||0379-6779||DOI:||10.1016/S0379-6779(00)01242-X||ISI #:||000168741500052||Category:||A1||Type:||Journal Contribution||Validations:||ecoom 2002|
|Appears in Collections:||Research publications|
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