Please use this identifier to cite or link to this item:
http://hdl.handle.net/1942/31424
Title: | Automated Polymer Synthesis Platform for Integrated Conversion Targeting Based on Inline Benchtop NMR | Authors: | RUBENS, Maarten VAN HERCK, Joren JUNKERS, Tanja |
Issue Date: | 2019 | Publisher: | AMER CHEMICAL SOC | Source: | ACS macro letters, 8 (11) , p. 1437 -1441 | Abstract: | An automated polymer synthesis platform based on an inline low-field nuclear magnetic resonance spectrometer is developed. Flow chemistry and automated inline analyses are an excellent combination for automated kinetic screening and for self-optimizing reactions with programmable conversion targeting. By monitoring monomer conversion over a continuous range of reactor residence times, the platform is able to construct kinetic profiles of polymerizations in an accurate and efficient way. The machine assisted self-optimization routine allows the reaction to be stopped at any given preselected conversion, giving rise to unprecedented reproducibility in polymer synthesis. | Notes: | Junkers, T (reprint author), Monash Univ, Sch Chem, Polymer React Design Grp, 19 Rainforest Walk, Clayton, Vic 3800, Australia.; Junkers, T (reprint author), Hasselt Univ, Inst Mat Res, Martelarenlaan 42, B-3500 Hasselt, Belgium. tanja.junkers@monash.edu |
Keywords: | Self-Optimization;Online;Spectroscopy;Reactors;System | Document URI: | http://hdl.handle.net/1942/31424 | e-ISSN: | 2161-1653 | DOI: | 10.1021/acsmacrolett.9b00767 | ISI #: | WOS:000498285200007 | Rights: | 2019 American Chemical Society. | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2020 |
Appears in Collections: | Research publications |
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acsmacrolett_9b00767.pdf Restricted Access | Published version | 927.48 kB | Adobe PDF | View/Open Request a copy |
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