Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/34531
Title: Scalable Aqueous Reversible Addition–Fragmentation Chain Transfer Photopolymerization-Induced Self-Assembly of Acrylamides for Direct Synthesis of Polymer Nanoparticles for Potential Drug Delivery Applications
Authors: ZAQUEN, Neomy 
Zu, Huijie
Kadir, Ak M.N.B.P.H.A.
JUNKERS, Tanja 
Zetterlund, Per B.
Boyer, Cyrille
Issue Date: 2019
Publisher: 
Source: ACS APPLIED POLYMER MATERIALS, 1 (6) , p. 1251 -1256
Abstract: The synthesis of polymer nanoparticles for potential drug delivery applications via photoinduced electron transfer-reversible addition-fragmentation chain transfer aqueous dispersion polymerizations employing Eosin Y/triethanol amine as catalytic system is described. A scalable synthesis procedure for the polymerization of poly(dimethyl acrylamide)-b-(poly(diaceteone-stat-dimethyl acrylamide)) is reported under visible light (lambda(max) = 530 nm). A variety of solid contents and block lengths for the solvophilic and solvophobic blocks are investigated, expanding the compositional space of worms, jellyfish, and vesicles using flow chemistry. A simple two-step process using a coupled flow reactor setup is used without the need for intermediate purification.
Keywords: photoPISA;PET-RAFT;flow reactor;morphology;polymer nanoparticles
Document URI: http://hdl.handle.net/1942/34531
ISSN: 2637-6105
e-ISSN: 2637-6105
DOI: 10.1021/acsapm.9b00280
ISI #: WOS:000476967000001
Category: A1
Type: Journal Contribution
Validations: ecoom 2022
Appears in Collections:Research publications

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