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Title: | Facile Aqueous Solution-Gel route toward Thin Film CuBi2O4 Photocathodes for Solar Hydrogen Production | Authors: | JOOS, Bjorn ELEN, Ken VAN DEN HAM, Jonathan Meulendijks, Nicole BUSKENS, Pascal PAULUS, Andreas WOUTERS, Koen MANCA, Jean D'HAEN, Jan SHUKLA, Sudhanshu VERMANG, Bart VAN BAEL, Marlies HARDY, An |
Issue Date: | 2023 | Publisher: | Wiley | Source: | Advanced Sustainable Systems, | Status: | Early view | Abstract: | A new benign aqueous route towards bismuth-containing photoelectrodes is proposed to eliminate the need for harmful organic solvents and/or acids. A CuBi2O4 photocathode was prepared by stabilizing the metal ions through complexation in pH neutral aqueous solutions. Merits of the proposed approach are elemental homogeneity (with unique doping possibilities) and ease of fabrication (e.g. high scalability). The prepared aqueous CuBi2O4 precursor forms a nearly phase-pure kusachiite crystalline phase free of organics residuals and capable of water reduction due to its sufficiently negatively positioned conduction band at -0.4 V vs. RHE. Deposition on FTO/glass substrates and thermal treatment leads to uniform but granular films of CuBi2O4 with excellent control over stoichiometry and thickness, owing to the facile and non-destructive synthesis conditions. Ultimately, the optimized CuBi2O4 photocathodes produced AM1.5G photocurrent densities of up to -1.02 mA∙cm-2 at 0.4 V vs. RHE with H2O2 as an electron scavenger, competing with bare CuBi2O4 prepared through less benign non-aqueous organic synthesis routes. | Keywords: | hydrogen;photoelectrochemical water splitting;semiconductors;solar fuels;solution-gel synthesis | Document URI: | http://hdl.handle.net/1942/40232 | ISSN: | 2366-7486 | e-ISSN: | 2366-7486 | DOI: | 10.1002/adsu.202300083 | ISI #: | 000999455300001 | Category: | A1 | Type: | Journal Contribution |
Appears in Collections: | Research publications |
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Advanced Sustainable Systems - 2023 - Joos - Facile Aqueous Solution‐Gel Route toward Thin Film CuBi2O4 Photocathodes for.pdf Restricted Access | Early view | 2.66 MB | Adobe PDF | View/Open Request a copy |
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