Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/15079
Title: Transfer Reactions in Phenyl Carbamate Ethyl Acrylate Polymerizations
Authors: Bennet, Francesca
Roelle, Thomas
Faecke, Thomas
Weiser, Marc-Stephan
Bruder, Friedrich-Karl
Barner-Kowollik, Christopher
JUNKERS, Tanja 
Issue Date: 2013
Publisher: WILEY-V C H VERLAG GMBH
Source: MACROMOLECULAR CHEMISTRY AND PHYSICS, 214 (2), p. 236-245
Abstract: The transfer reactions occurring during polymerization of 2-(phenylcarbamoyloxy)ethyl acrylate (PhCEA) were studied by a detailed product mapping with electrospray ionization mass spectrometry (ESI-MS). Unlike postulated before, PhCEA exhibits the same characteristic transfer reactions as other acrylic monomers at elevated temperatures, resulting in vinyl-terminated and saturated products. Transfer to monomer via abstraction of a hydrogen atom from the ester side chain as suggested before is not observed. When polymerized in a poly(ethylene glycol) (PEG) matrix to increase viscosity, transfer into matrix products are observed in minor amounts, demonstrating that PEG can be employed as a solvent to further increase the overall rate of polymerization without interference from side reactions.
Notes: [Bennet, Francesca; Barner-Kowollik, Christopher; Junkers, Thomas] KIT, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany. [Roelle, Thomas; Faecke, Thomas; Weiser, Marc-Stephan; Bruder, Friedrich-Karl] Bayer Mat Sci AG, Leverkusen, Germany. [Junkers, Thomas] Univ Hasselt, Polymer React Design Grp, Inst Mat Res, B-3590 Diepenbeek, Belgium.
Keywords: acrylate polymerization; electrospray ionization mass spectrometry; transfer to polymer;Polymer Science; acrylate polymerization; electrospray ionization mass spectrometry; transfer to polymer
Document URI: http://hdl.handle.net/1942/15079
ISSN: 1022-1352
e-ISSN: 1521-3935
DOI: 10.1002/macp.201200285
ISI #: 000313726500012
Category: A1
Type: Journal Contribution
Validations: ecoom 2014
Appears in Collections:Research publications

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