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Title: | Elements of RAFT Navigation | Authors: | HAVEN, Joris Hendrikx, Matthew JUNKERS, Tanja Leenaers, Pieter J. Tsompanoglou, Theodora Boyer, Cyrille Xu, Jiangtao Postma, Almar Moad, Graeme |
Issue Date: | 2018 | Publisher: | AMER CHEMICAL SOC | Source: | Matyjaszewski, K Gao, H Sumerlin, BS Tsarevsky, NV (Ed.). REVERSIBLE DEACTIVATION RADICAL POLYMERIZATION, VOL 2: MECHANISMS AND SYNTHETIC METHODOLOGIES, AMER CHEMICAL SOC,p. 77-103 | Series/Report: | ACS Symposium Series | Abstract: | This paper focuses on one of the next directions in the evolution of reversible addition-fragmentation (RAFT) polymerization, namely, progress towards the synthesis of discrete or uniform, sequence-defined (co)polymers. Following a brief review of RAFT-single unit monomer insertion (RAFT-SUMI), we describe recent developments in the field. We point to difficulties in achieving consecutive RAFT-SUMI and report two strategies for overcoming the issue of initiator-derived by-products. We show that the selection of RAFT agent is critical in selective RAFT-SUMI of N,N-dimethylacrylamide (DMAm) into a trithiocarbonate in aqueous solution. Finally we recount on the use of photoRAFT- or PET-RAFT-SUMI in the high yield synthesis of discrete oligomers comprising two or more consecutive SUMI steps. | Notes: | [Haven, Joris J.; Hendrikx, Matthew; Leenaers, Pieter J.; Tsompanoglou, Theodora; Postma, Almar; Moad, Graeme] CSIRO Mfg, Res Way, Clayton, Vic 3168, Australia. [Haven, Joris J.; Junkers, Tanja] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia. [Haven, Joris J.; Junkers, Tanja] Univ Hasselt, Inst Mat Res, B-3590 Diepenbeek, Belgium. [Hendrikx, Matthew; Leenaers, Pieter J.; Tsompanoglou, Theodora] Eindhoven Univ Technol, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands. [Boyer, Cyrille; Xu, Jiangtao] Univ NSW, Ctr Adv Macromol Design, Sch Chem Engn, Sydney, NSW 2052, Australia. [Boyer, Cyrille; Xu, Jiangtao] Univ NSW, Australian Ctr NanoMed, Sch Chem Engn, Sydney, NSW 2052, Australia. | Document URI: | http://hdl.handle.net/1942/28910 | ISBN: | 9780841233232 | DOI: | 10.1021/bk-2018-1284.ch004 | ISI #: | 000456766500004 | Rights: | 2018 American Chemical Society | Category: | C1 | Type: | Proceedings Paper | Validations: | ecoom 2020 |
Appears in Collections: | Research publications |
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