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http://hdl.handle.net/1942/29086| Title: | Photoiniferter Surface Grafting of Poly(methyl acrylate) using Xanthates | Authors: | RAMAKERS, Gijs RUBENS, Maarten KRIVCOV, Alexander Möbius, Hildegard Trouillet,Vanessa Welle,Alexander JUNKERS, Tanja |
Issue Date: | 2019 | Publisher: | WILEY | Source: | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 57 (18), p. 2002-2007 | Abstract: | The UV-induced and catalyst-free photoiniferter surface grafting using xanthate RAFT agents is studied. First, a novel silane containing a xanthate RAFT agent moiety is synthesized and successfully grafted onto a silicon wafer as confirmed by secondary ion mass spectrometry (SIMS). Next, using only methyl acrylate, solvent and UV light (365 nm) polymer brushes are grafted rapidly from the surface with film thicknesses up to 25 nm reached within half an hour. The obtained polymer films are thoroughly analyzed by X-ray photoelectron spectroscopy (XPS), ToF-SIMS, and AFM. | Notes: | Junkers, T (reprint author), Hasselt Univ, Inst Mat Res, Martelarenlaan 42, B-3500 Hasselt, Belgium. Monash Univ, Sch Chem, Polymer React Design Grp, Rainforest Walk 19, Clayton, Vic 3800, Australia. tanja.junkers@monash.edu | Keywords: | iniferter;photoiniferter;photopolymerization;polymer brushes;RAFT;surface functionalization;surface grafting;UV-initiation | Document URI: | http://hdl.handle.net/1942/29086 | Link to publication/dataset: | https://onlinelibrary.wiley.com/doi/abs/10.1002/pola.29405 | ISSN: | 0887-624X | e-ISSN: | 1099-0518 | DOI: | 10.1002/pola.29405 | ISI #: | 000486314800018 | Rights: | 2019 Wiley Periodicals, Inc | Category: | A1 | Type: | Journal Contribution |
| Appears in Collections: | Research publications |
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| Photoiniferter surface grafting of poly(methyl acrylate) using xanthates.pdf Restricted Access | Published version | 1.64 MB | Adobe PDF | View/Open Request a copy |
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