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Title: | Radical as well as anionic polymerisation mechanisms in the synthesis of poly(p-arylene vinylene) precursors | Authors: | HONTIS, Lieve Van der Borght, M VANDERZANDE, Dirk GELAN, Jan |
Issue Date: | 1999 | Publisher: | ELSEVIER SCI LTD | Source: | POLYMER, 40(23). p. 6615-6617 | Abstract: | Experiments have been performed to clarify the polymerisation mechanism of chloromethyl-4-(n-butylsulfinyl)methylbenzene 1a and 4-chloromethyl-4'-(n-butylsuIfinyl)methylbiphenyl Ib in NMP. Addition of TEMPO and water to the polymerisation mixture led to the conclusion that radical as well as anionic mechanisms occur which lead to the formation of a high and a low molecular weight polymer fraction, respectively. (C) 1999 Elsevier Science Ltd. All rights reserved. | Notes: | Limburgs Univ Ctr, Lab Organ & Polymer Chem, Div Chem, B-3590 Diepenbeek, Belgium.Vanderzande, D, Limburgs Univ Ctr, Lab Organ & Polymer Chem, Div Chem, Univ Campus, B-3590 Diepenbeek, Belgium. | Keywords: | polymerisation mechanism; p-quinodimethane systems; poly(p-arylene vinylene) precursors | Document URI: | http://hdl.handle.net/1942/3016 | DOI: | 10.1016/S0032-3861(99)00242-6 | ISI #: | 000082132800041 | Type: | Journal Contribution | Validations: | ecoom 2000 |
Appears in Collections: | Research publications |
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